棉籽油脱臭馏出物中提取维生素E和植物甾醇-化学工艺专业毕业论文.docxVIP

ABSTRACT Cottonseed Oil Oeodorizer Distillate(CODD) is the byproduct of cottonseed oil refining process，mainly containing 仕ee fatty acid，natural vitamin E，phytosterols and glyceride et al. Natural vitamin E and phytosterols due to their physiological activity play major roles in several areas，namely in pharmaceuticals ，food ，cosmetics and e如 feed. The pu巾。盹 of the thesis is to study technics of separating vitamin E and phytosterols from COOD. The operation condition of specific adsorption and crystallization for separation vitamin E and phytosterols respectively have been e studied. According to the National Standard，the physicochemicaI properties of CODO have been analyzed as follows: water and volatile matt町 0.920%，acid value 71.1 mgKOH饵， saponificaton value 133 mgKOH倍， glyceride content 35.0%，vitamin E content 5.97%，phytosteroIs content 12.3%. In the same condition，macroporous resin D1 has better performance of specific static adso甲tion. ηrrough dynamic adsorption in a fixed bed，adsorption agents and the flow rate of ethanol have been compared. The results showed that COγethanolωdesorption agents is better than 5%(v%)acetic acid-ethanol ，and the sui阳.ble flow rate is O.5BV斤1. In the optimaI condition， the purity and yield of vitamin E are 76.6% and 91.6%， respectively. After readsorption ，the purity and yield ofvitamin E are 78.7% and 99.4%， 、respectively. 、 Using the adsorption byproduct as material，the optimal conditions for crystallization are: the solvent of ethyl acetate; the proportion of crystallization material to the solven俨 1:5(weightωvolum); the tempera阳re -5 .C; the time for cooling 96 h. The experiment results of recrystallizingphytosterol in ethyl acetate showed that the purity and the yield were 77.3% and 52.1%，respectively. KEY WORDS: Deodorizer Distillate，vitamin E，adsorption ，ph抖。如时， crystallization 目录 前宫…川…川………，，…… 1 第一章文献综述 川…………..……川……...川………..，.… 川……………… 川.…川…...…...……川川….……..川…... A楠 A楠、 Ir;1 ，. |‘ 1.1 脱臭锢