萃取精馏分离甲基环己烷和甲苯工艺过程的模拟.docxVIP

萃取精馏分离甲基环己烷和甲苯工艺过程的模拟 张春勇，郑纯智，唐江宏，张国华，单万建( 萃取精馏分离甲基环己烷和甲苯工艺过程的模拟 张春勇，郑纯智，唐江宏，张国华，单万建 ( 江苏技术师范学院 江苏省贵金属深加工技术及应用重点建设实验室，江苏 常州 213001) ［摘要］ 利用 Aspen Plus 流程模拟软件，采用双塔流程，以苯酚为萃取剂，对萃取精馏分离甲基环己烷 ( M C ) 和甲苯 ( M B ) 的过程 进行模拟计算，并用实验验证。考察了萃取精馏塔的萃取剂进料位置、原料进料位置、萃取剂与原料的摩尔比 ( 溶剂比) 和回流比 等因素对分离效果的影响。在满足 M C 产品的纯度和收率均达到 99% 的条件下，模拟优化的结果为: 理论塔板数为 24 块，原料在 第 17 块板进料，萃取剂在第 5 块板进料，溶剂比 3． 08，回流比 5。模拟结果与实验数据吻合较好，说明采用的模拟方法适用于 M C 和 M B 混合物萃取精馏过程的模拟。 ［关键词］ Aspen Plus 软件; 模拟; 萃取精馏; 甲基环己烷; 甲苯 ［文章编号］ 1000 － 8144( 2011) 05 － 0532 － 04 ［中图分类号］ TQ 028． 1 ［文献标识码］ A Process Simulation of Extractive Distillation for Methylcyclohexane and Toluene System Zhang Chunyong，Zheng Chunzhi，Tang Jianghong，Zhang G uohua，Shan Wanjian ( Jiangsu Key Laboratory of Precious M etal Chemistry and Technology， Jiangsu Teachers University of Technology，Changzhou Jiangsu 213001，China) ［Abstract］ Extractive distillation process for methylcyclohexane( M C) and toluene( M B) system w as simulated by using Aspen Plus softw are． Phenol w as chosen as the extractant． A process w ith tw o columns，namely extractive distillation column and solvent recovery column， w as designed for separating the mixture． Effects of the extractant feed position and the mixture feed position on the extractive distillation column，the mole ratio of extractant to feedstock( solvent ratio ) ，and the reflux ratio on the extractive distillation w ere investigated． Aimed at the M C mole fraction of 99% in the products and the M C recovery of 99% ，the extractive distillation process w as simulated to obtain the optimal conditions for the extractive distillation column as follow s，number of theoretical plates 24，the mixture feed at 17th plate，the extractant feed at 5th plate，the solvent ratio 3． 08 and reflux ratio 5． The extractive distillation simulation result w as verified by the experiment data． ［Keywords］ Aspen Plus; simulation; extractive distillation; methylcyclohexane; toluene 甲基环己烷 ( M C ) 和甲苯 ( M B ) 是非常重要的 精细有机化工原料和