离子液体电沉积铝微观形貌研究-分析化学专业毕业论文.docxVIP

PAGE PAGE III deposition, scanning electron microscope(SEM), X-ray diffraction(XRD), ultraviolet– visible spectroscopy(UV-Vis) and nuclear magnetic resonance(NMR) was conjectured .The results showed that: Methyl carbamate as an additive would make grain refinement more apparent and present more strong Al (200) crystal plane orientation. As an additive, methyl carbamate did not form new metal complex in the electrolytic liquid and did not affect the structure of active aluminum ion in the electrolyte. The positive center of carbonyl carbon atom in methyl carbamate molecular can be easily adsorbed at the cathode surface. This procedure inhibited the process of Al deposition and obtained the smooth and bright effect. Therefore, Al deposition layer of mirror can be obtained, which has an important guiding significance in the selection of ionic liquid additive in electrodeposition system. At the same time, a series of organic molecules containing sulfinyl as additives of ionic liquids electrodeposition of aluminum were investigated. The analysis of different mechanism by comparing with adsorption of additives. The study found: Dimethyl 3+ sulfone complexation with AlCl3 form new Al(DMSO2)3 metal complex ion. This kind of complex ion did not make the surface of Al deposition layer became smooth and bright. On the contrary, the surface of the deposition layer became more rough and easier to form dendrites. Although using the method of pulse electrodeposition of aluminum from ionic liquid had the potential advantage. But there was no literature to be reported the essence of pulse polarization process. There was also the lack of systematic research on the process of aluminum deposition and the change of morphology. Therefore, this paper analysed the aluminum deposition process and morphology under different time, current density, voltage, quantity of electric charge by the method of constant current, constant potential, galvanostatic pulse, constant volt