离子液体用于乙酸乙酯与乙醇共沸体系分离的汽液平衡研究-化学工程与技术专业毕业论文.docxVIP

北京化工大学硕士学位论文验数据结果显示，当加入的离子液体含量为0．15时，三种离子液体均可 北京化工大学硕士学位论文 验数据结果显示，当加入的离子液体含量为0．15时，三种离子液体均可 打破乙酸乙酯．乙醇的共沸点。而对于乙酸乙酯．乙醇体系，【MMIM][DMP】 的分离效果最好，[EMIM][DEP]、【BMIM][DBP]依次减弱。 采用电解质有规双液模型(e．NRTL模型)对实验测定的二元及三元 体系的实验数据进行了关联。对比分析二元和三元体系的实验值和 e．NRTL模型关联的计算值，结果表明e-NRTL模型能够用来描述二元和 三元体系的热力学行为，并且数值准确可靠。 实验结果表明，三种磷酸酯类离子液体能够应用到乙酸乙酯与乙醇共 沸体系的分离工艺中。 关键词：离子液体，乙酸乙酯，乙醇，汽液相平衡，e．NRTL方程 II 万方数据 ABSTRACTSEPARATIoN ABSTRACT SEPARATIoN oF ETHYL ACETATE．ETHANoL AND MEASUREMENT OF VAPOR-LIQUID EQUILIBRIUM WITH IONIC LIQUIDS ABSTRACT As one of most widely used ester,ethyl acetate was manufactured along with a lot of ethan01．Ethyl acetate and ethanol form a minimum-boiling azeotropic systems at atmospheric pressure，and its difficult to use the traditional separation methods to separate the azeotrope．The key of extractive distillation is choosing the entertainer．The disadvantages of organic solvents included large usage，etc．Ionic liquids(ILs)are organic salts in room temperature and have special properties，such as negligible vapor pressure and solubility in polar and nonpolar compounds，etc．Apart from that，they have outstanding salting·-out or salting·-in for azeotropic systems and can be easily separated and recycled．Recently,some scholars focused on the separation using ILs as entrainers． In this work，three kinds of ILs were selected as entrainers using in the separation of ethyl acetate and ethanol，namely 1-methyl-3-methylimidazole dimethylphosphate([MMIM][DMP])，1-ethyl-3-methylimidazole diethyl— III 万方数据 万方数据 万方数据 北京化工大学硕士学位论文phosphate([EMIM][DEP])，1-butyl-3-methylimidazole 北京化工大学硕士学位论文 phosphate([EMIM][DEP])，1-butyl-3-methylimidazole dibutylphosphate ([BMIM][DBP])．Isobaric vapor-liquid equilibrium data for binary and ternary systems were measured by using a vapor-liquid equilibrium still (CE一2)and separation efficiency of them is investigated． The VLE data of binary systems in constant pressure were measured， including ethyl acetate-ethanol，ethyl acetate-IL and ethanol-IL．The result showed that