锂离子电池碳负极材料的制备及其电化学性能的研究-应用化学专业论文.docxVIP

万方数据 万方数据 g/cm3；比表面积由 8.194 m2/g 降低到 8.103 m2/g。随着热处理温度的升高， 酚醛树脂碳化越来越完全，包覆石墨的电化学性能更好。将酚醛树脂包覆 石墨后再进行液相氧化改性，结果表明，在 1 C 电流密度下，首次充放电 容量分别为 382.8 mAh/g 和 349.4 mAh/g，首次充放电效率达到 92 %，经 过 10 次放电循环后容量保持在 96.2 %以上，在电流密度为 1/2 C 时，经过 30 次放电循环后容量保持率为 94 %。 关键词：锂离子电池；负极材料；天然石墨；氧化改性；酚醛树脂包覆 Abstract In this thesis, the modification of natural graphite, which had good lithium-storage performance but bad compatibility with electrolyte, was studied. X-ray diffraction (XRD), Scanning electron microscope (SEM), and so on was used to analyze the structure of natural graphite. Natural flake graphite was modified by gas-phase and liquid-phase oxidation to improve its cycle performance. Tap density of natural flake graphite was improved and the ratio of surface area was reduced by phenolic resin coating. The electrochemical performances of as-synthesized composite materials were studied primarily. The electrochemical performances of natural graphite were measured. It was showed that SEI films which formed in the first cycle could inhibit further decomposition of solvent and avoid the exfoliation of graphite flake in the electrolyte during cycling. Therefore, at lower current density natural flake graphite exhibited better electrochemical performance. Natural graphite was oxidized by air and H2O2. It showed that lithium-storage sites increased and the particle size became more uniform by air oxidation. These changes made the insertion capacity increase and were beneficial to form stable and uniform SEI film. It was proved that the oxygen content on the surface of the graphite increased after H2O2 oxidation treatment. The change of surface structure was beneficial to decrease the consumption of Li-ion when SEI film formed in the initial charge process. Furthermore, this change inhibited the decomposition of solvent and electrolyte and increased the coulombic efficiency in the first cycle. In the current density of 1/10 C, the first irreversible capacity of natural graphite modified by H2O