拉伸成孔制备聚合物粒子PET复合光反射膜的研究-化学专业论文.docxVIP

西南科技大学硕士研究生学位论文第 西南科技大学硕士研究生学位论文 第 PAGE IV 页 西南科技大学硕士研究生学位论文第 西南科技大学硕士研究生学位论文 第 PAGE III 页 Abstract Light reflective film is an important component of liquid crystal display backlight (LCD), playing an extremely important role in the (LCD). Firstly, according to the concept of solubility parameters , ten kinds of typical polymers which have different solubility parameter with PET were selected as the fillers .The fillers were added into the PET matrix, granulating and filming by drooling. The film was biaxially stretched under certain conditions (such as temperature, draw ratio, etc.) is biaxially stretched, obtaining the light reflection film with pores inside. The light reflection performance and the changes between internal and external structure were determined.To choose a light reflective particle with better performance. The preparation process and properties of the polymer particles/PET thin film were studied to get the best process and formula combined with the UV - visible - near infrared spectrophotometer,SEM,optical lens, thermal gravimetric analysis,universal mechanical testing machine.the mechanism of the reflection properties produced by the pore structure of polymer particles/PET film was simply discussed. In the experimental section, the mechanism of the increasing reflectivity of the thin film was preliminary studied , and the best reflective particle was selected from the ten. Experimental results show that: the main factors affecting the reflectivity of the film after stretching is the difference of the solubility parameter. When the difference of solubility parameter between the polymer particle and PET is 1.6-9.2 (J/m-3) 1/2, the reflectivity of the film increases with the increasing of the solubility parameter difference. Pore structure formed by the film stretching is beneficial to improve the reflective properties of the film. PP and TPX are the reflective particles which are suitable for forming pore structure by film stretching. Subse