梁滩河罗家坝桥断面底泥重金属Pb和Zn的吸附解吸规律分析及风险评价-环境科学与工程专业论文.docxVIP

重庆大学 重庆大学硕士学位论文 英文摘要 PAGE PAGE VI ABSTRACT Heavy metals can react with many anions and organic polymers in water, forming coordination complexs and chelates with strong absorbability to be fixed in the sediments. When the water environment changed, heavy metal stayed in the surface of the sediment particles could release to the water easily, causing secondary pollution. Due to its difficult biodegradation and long incubation, heavy metals can cause direct and indirect harm to human beings and creatures. Targeted the sediments at Luojiaba section of Liangtan River, this research aimed to study absorption and desorption rule and dynamic characteristic of Pb and Zn, their morphologic change during absorption and desorption, realize the contamination status and ecological risk feature. After analyzing the physicochemical properties of the sediments, we know that: the pH of the sediments is 6.86; the main heavy metal elements are Pb、Cr、Zn、As、Ba and Mn, whereas Cu、Cd and Hg are not detected, and the quantity of Cr、Pb、Zn and Mn is higher than the background value of soil; the organic content is 3.71%; CEC is 256.33mol/kg; and the main form of Pb and Zn is residual form, which is up to 70%, then organic combined state, whereas the quantity of carbonate combined state of Pb and Zn is the least. By operating isothermal adsorption and desortion experiment, we get the following conclusions: the rule of isothermal adsorption process between both sediments and Pb with sediments and Zn is as equilibrium concentration increase adsorbing capacity increse rapidly when the initial concentration is low, and the adsorbing capacity increse slowly when the initial concentration is high; the sediments absorbed Pb more easily than Zn; Freundlich equation can describe the isothermal adsorption process properly, but Langmuir equation is unfit for description of the process; the desorption quantity of Pb and Zn increase with the absorption amount increasing, when the absorption amount is sm