磷酸铁锂性能衰减与恢复分析-材料工程专业论文.docxVIP

华 华 中 科 技 大 学 硕 士 学 位 论 文 II II 颗粒表层进行一定量的蔗糖包覆并在 720℃条件下烧结，实验结果显示磷酸铁锂 0.2C 放电比容量接近 150mAh/g。 关键词：LiFePO4 ,受潮处理,气流粉碎, 热处理, 碳包覆层,性能恢复 III III Abstract LiFePO4 is still the one of the focus of the current study because of it’s advantages such as the high energy, high operating voltage, good safety performance, envoronmental friendly, low cost and so on, also account for a certain proportion of the market. With the mature of production technology, the yied of LiFePO4 is incresing. the storage problem worthy of attention and research.as known to all, low intrinsic conductivity restricts its widespread use, the modified methods are varied, also decide the factors influencing the performance of LiFePO4 are varied, on the basis of the analysis, the paper mainly study the influence of moist air and air-crushed treatment on the LiFePO4. Explore the influence of damp treatment to the LiFePO4 and its precursor spray powder, which are put into the constant humidity environment. weigh some LiFePO4 to make the button batteries, compare the difference of electrochemical properties between before damp and after, analysis the influence of treatment time on properties. Sinter the precursor spray powder at the 720℃,then make button batteries to compare the electrochemical properties, use the thermal stability analysis method(TG-DSC) and structure and morphology analysis method(XRD,SEM) to study the performance degradation and recovery mechanism, finally find the best method to recover the performance. Explore the influence of air-crush treatment on the structure and performance, use the C12H22O11 to make carbon coating , to decide the sinter temperature by TG-DSC, make the structure and morphology analysis by XRD,SEM, raman spectroscopy, summarize the performance degradation and recovery mechanism. Studies show that the performance of LiFePO4 have degradation after damp treatment, the degradation is worse with the extension of time. But after some appropriate treatment, the performa