锂离子电池气体发生行为的分析-化学工程与技术专业论文.docxVIP

哈尔滨工业大学工程硕士学位论文 哈尔滨工业大学工程硕士学位论文 II II Abstract With the development of electric vehicles, the safety performance of lithium ion battery becomes even more serious. In the process of charging and discharging, the gas produced by the battery constituted one of the most harmful factors for battery security. On the basis of reviewed the safety performance of the battery, we carry out both MS and IR to characterize and discuss the generation of the gas in the lithium ion battery. In the bottle battery, we analyzed the production of gas in the various stages. The study found that: in the formation stage, the gas produced from 2.5V. EC in the voltage begins to decompose solid material such as lithium carbonate generated, along with the gases of C2H2. At the same time, the electrolyte in the presence of H2O will result in the formation of H2 and CO2 gas. In the voltages of 2.5~3V, CH4 and C2H6 was generated, it indicated the decompose of DEC and EMC to form the SEI film. However, the mass spectrometry test of C2H4 is the largest, indicating that the EC at this stage is still the main component of the film. Into voltage for 3~3.5V, C2H4, CH4 and C2H6 production is roughly equal, indicating that three kinds of electrolyte components are beginning to play a role in this voltage range for main range of the film. In the voltage range of 3.5~4.2V, the amount of gas goes to the trend of slow growth, indicating that the SEI film has been basically completed in this voltage range. CaF2 battery was designed for the infrared test of the gas in the battery. For negative, we have different electrolytic material to test gas generated by the SEI film formed in the different electrolyte system. Found that the gases were mainly determined by the electrolyte not by the electrode materials. We also investigated the film-forming in different temperature and current. We found that the lower temperatures, smaller currents are beneficial to the film formation of the SEI film, leading to the genera