离子液体的合成及在酯化转酯反应中的应用-应用化学专业论文.docxVIP

11 11 摘要 设计…种高泪反应和低温分离相结合的乙酸辛酣合成路线。通过研究各种因素对 1-辛醇转化率的影响，获得合成乙酸辛醋的最佳反应条件(温度: 3S.C ，酶用量: 2Omg， 离子液体用最:1.饨，反应时间:饨，含水量: 1%) 。在此最佳条件下， 1-辛酵的转化 率达 99.3%，自尊在 [D(2-mb)Im][PF6]中的稳定性是正己;院中的 8.3 倍，离子液体可重复使 用 5 次催化活性没有明显的降低。此外，因工色谱和内源荧光光谱被应用于不同介质 中脂肪酶结构变化，结果表明酶在 [D(2mb)Im][PF61中有较大的氨基酸残基裸露程度和 良好的二级结构稳定性。 关键词:离子液体;棕榈油酸多元醉酶:可生物降解润滑剂:乙酸辛醋:非水生物 催化 Ab Abs衍act Abstract Ionic liquids are new types of environment仕iendly materials and can be used as cata1ysts as well as biological response of the green non-aquωus media. At present，ionic liquids have been successfully applied to many difl伽ent areas，such as organic synthesis， biocatalysis reaction，s叩aration process，electroch臼nistry etc. In addition， ionic liquids can resolve 阳increasingly s创ous environmenta1 problems，improve product qua1ity and reduce the ωst of production.ηlerefore ，it is significance to degisn 由e new ionic liquids with special function 由at can satis命 the various demands and enrich the 位mdamental thωry about the ionic liquids. In this work，we designed and synthesized five acidic ionic liquids including two no reportedωmposite ionic liquids，sulfuric acid-l ，3-din-pentylimidazolium tetrafluoroborate (H2S04-[D(n-Cs)hn ]阴阳]) and phosphoric acid-l ，3-di-n-pentylimidazolium tetrafluoroborate (H3P04-[D(n-Cs)hn ]阴阳])， and three new 1，3-dipenty1imidazolium hexafluorophosphate ionic liquids isomers，1，3-di刑-pentylimidazolium hexafluorophosphate ([D帜-Cs)hn][PF6])， 1，3-di-isopentylimidazolium hexafluorophosphate([D(i-Cs)Im] [PF6]) and 1，3-di(2methylbutyl)imidazolium hexafluorophosphate ([D(2-mb)Im] [PF6]). We taken no solvent and t臼np町a阳re programmed to improve traditional two-step synthesis method which improved product purity，and we obtain肌1 that the speed of intermediate product 1，3-dialkyl imidazolium bromide ([Rlm][Br]) gen町ated was the control response. After we characterized the products by using in仕ared spectroscopy and NMR，we researched the physical and chemical prop创邸， including polarity，viscosity ，wat