氧化锌矿物碱法提取新工艺研究.pdfVIP

ABSTRACT With oxide the ofZincsulfide increasingshortage ore，Zinc resourcesare and atthestatusthat gradually utilized．Aiming developed inZincoxidemineiSdi衔culttodealwith．we a hemimorphite proposed newalkaline totreat carriedout process hemimorphite，andsystematic conditionsandtheoreticalstudies．Thecontentsareasfollows： specific the of analized Zn—Si—H20 1)．DrawedlgC-pHdiagram system，and t11e conditionswithcausticsodatotreat thermodynamic hemimorphite． thatin of and W．ecanleam alkaline lcachingprocesshemimorphite．Zn siliconenteredintosolutionwith Zn(O均42’and Wrealsostudiedits mechanism．anddetermineditsactivation dynamics E=45．7 reactionorder showedthat energy kJ／mol，the n=1．4，which the wascontrolledchemicalreaction． leachingprocess by the flowwithAlkalinetotreatlow．silicon 2、)．Designedprocess of Zninalkalisolutionfromlow．silicon a11．extract hemimorphite．First inahotballmillreactor．Inordertocontrolthe of hemimorphite leaching wasaddedinto solutionthe Si02，CaO Na0H duringleachingprocess． ⅥmenCaO is1timeofthetheoretical