越南钛铁矿的熔融特性.pdfVIP

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  • 2019-06-13 发布于江苏
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中国工程热物理学会 燃烧学 学术会议论文 编号:184261 越南钛铁矿的熔融特性 1 1 1 1 1 1* 2 1 刘磊 ,成茂 ,陈虎 ,王会 ,李烨 ,李振山 ,李维成 ,蔡宁生 (1.清华大学能源与动力工程系热科学与动力工程教育部重点实验室,北京市,100084;2.四川省清 洁燃烧与烟气净化重点实验室,四川·成都,611731) lizs@mail.tsinghua.edu.cn) 1 摘 要 载氧体的熔融状态限制了化学链燃烧反应器运行温度的上限。本文提出采用可视化的熔融实 验系统,实验探究越南钛铁矿在不同气氛下的熔融特性,并使用 Factsage 软件进行热力学计算。结果 表明,氧化态和还原态越南钛铁矿达到变形温度后均会在30℃内,甚至10℃内迅速融化,实际燃料反 应器和空气反应器的温度必须严格低于还原态越南钛铁矿的变形温度,1363℃。氧化态钛铁矿在还原 性气氛下,熔融特性温度会明显降低;还原态钛铁矿在空气中,熔融特性温度会增加约150℃。 关键词:化学链燃烧,载氧体,钛铁矿,熔融特性 The melting characteristics of Vietnamese ilmenite used in chemical looping combustion 1 1 1 1 1 1 2 1 LIU Lei , CHENG Mao , CHEN Hu , WANG Hui , LI Ye , LI Zhenshan , LI Weicheng , CAI Ningsheng 1 Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Energy and Power Engineering, Tsinghua University, Beijing 100084, China 2 Dongfang Electric Group Dongfang Boiler Company Limited, Zigong 643001, China ABSTRACT: The melting state of the oxygen carrier limits the upper limit of the operating temperature of the chemical looping combustion reactors. In this paper, a visualized melting experimental system was used to explore the melting characteristics of Vietnamese ilmenite in different atmospheres, and the thermodynamic calculation was performed using Factsage software. The results show that both the oxidized and reduced states of ilmenite will melt rapidly within 30 °C or even 10 °C after reaching the deformation temperature. And the actual temperature of the

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