木竹与溴系阻燃塑料衍生吸附剂的制备及其脱汞性能研究.docxVIP

中国工程热物理学会 燃烧学 学术会议论文 编号：184124 木竹与溴系阻燃塑料衍生吸附剂的制备及其脱汞性能研究 胡靖远，许洋，邓芳芳，庞淇聪，何双无，罗光前*，朱贤青，李显，姚洪* （华中科技大学 煤燃烧国家重点实验室，武汉 430074） (Tel: 027 Email: guangqian.luo@hust.edu.cn) 摘 要 本文以城市固体废弃物中的木竹和溴系阻燃（BFR）塑料为原料，采用共热解法制备含溴脱汞吸附剂（Br-biochars），探究了热解温度、混合比例及烟气组分对脱汞性能的影响，该方法可实现废弃物的资源化利用。研究发现：热解过程中，BFR和生物质发生会交互作用，BFR中的溴以Br―和C-Br键的形式被固定在Br-biochars中，使得其脱汞性能大幅提升且商业活性炭接近。XPS、TPD及吸附动力学研究表明：脱汞过程中化学吸附起主导作用，C-Br官能团可将Hg0氧化为HgBr2。 关键词 汞；生物焦；城市固体废弃物；热解；溴； Abstract A novel method using one-step pyrolysis of waste biomass and brominated flame retarded (BFR) plastic was proposed to prepare brominated biochars (Br-biochars) for elemental mercury (Hg0) removal from coal-fired flue gas. This method could simultaneously realize the disposal of municipal solid waste and the preparation of mercury sorbents. The sample characterization showed that an interaction effect between BFR plastic and biomass occurred during the co-pyrolysis process. The addition of BFR plastic would deteriorate the pore structure of sorbents because the melted plastic residues were aggregated on their surface. And Br emitted from BFR plastic was fixed into the co-pyrolyzed chars in the form of Br– and C–Br group. Br-biochars exhibited far better Hg0 removal performance compared to virgin biochars. The optimum pyrolysis temperature and plastic/biomass mass ratio were 600 oC and 1:1, respectively. The effects of adsorption temperature and individual flue gas on Hg0 removal performance were also explored. The Hg0 adsorption capacity of Br-sorbents was close to those of commercial activated carbons. Both the experimental data and kinetic model showed that the Hg0 adsorption over Br-biochars was mainly controlled by chemisorption, where C–Br bonds were the active sites for oxidizing Hg0 into HgBr2. This was confirmed using mercury temperature programmed desorption experiments. Keywords: Mercury