不同密度的原木和烘焙木单颗粒燃烧实验.docxVIP

不同密度的原木和烘焙木单颗粒燃烧实验 Single particle combustion of wood and torrefied wood with different apparent density 卢志民1,2*，简杰1，吴昊3*，Peter Arendt Jensen3, Peter Glarborg3 1华南理工大学电力学院，广州510640 2浙江大学清洁能源利用国家重点实验室，杭州310027 3Department of Chemical and Biochemical Engineering, Technical University of Denmark, S?ltofts Plads 229, 2800 Kgs. Lyngby, Denmark 通讯作者电话：(86)邮箱：zhmlu@ 摘要 本文通过模拟粉末燃料锅炉的工况条件（1256°C, 2.8vol% O2, 27vol% H2O），研究了5种密度不同（243-698kg/m3）的木颗粒烘培前后的着火时间，挥发分与焦炭的燃烧时间以及焦产率等燃烧特性。实验条件下，着火和挥发分燃烧的时间随颗粒质量和密度的增加呈线性增长。与原木相比，烘焙会使木颗粒的焦产量显著增加。焦炭燃烬时间主要受其颗粒质量的影响，亦部分受焦反应性的影响。本研究显示木颗粒密度对燃烧特性的影响比有机和无机组分更大。 Abstract Single particle combustion experiments on 3 mm raw and torrefied wood particles of 5 different wood species with apparent density varying from 243 to 698 kg/m3 were conducted, under conditions (1256 °C, 2.8vol% O2) simulating a pulverized fuel boiler. Times for ignition, flaming devolatilization, char combustion, along with char yield and char reactivity, were determined. At the investigated conditions, ignition and devolatilization times increased linearly with particle mass, thereby the density differences between different wood species and between raw and torrefied wood strongly influenced the ignition and devolatilization times. Torrefaction also led to a marked increase in char yield at high temperatures compared to the char yield of raw wood. The char burnout time was mainly proportional to the mass of char particles, with a small influence of the char reactivity. The study indicates that the wood density have a much larger influence on combustion properties than the carbohydrate and inorganic compositions. The fuel potassium content do have some influence on char yield and char reactivity. 关键词：木种，密度，烘焙，焦产率，焦炭燃烧 1引言 生物质代替煤作为锅炉燃料可以降低CO2，NOx和SO2的排放[1,2]。2015年，欧盟有159座发电厂和热电联产电站使用固体生物质（木颗粒，木屑等）燃料，通过单独燃烧或者与煤混烧的方式发电，欧盟58%的可再生能源发电都来源于生物质[3]。许多热电联产机组原来都是使用高效的煤粉锅炉，而木质生物质被认为是最方便和最优质的生物质燃料。 对木质生物质粉末燃料而言，受限于锅炉的停留时间，必须使包括着火，挥发分燃烧和焦燃烧在内的整个燃烧过程在很短时间内完成。然而与大量的热解和燃烧动力学研究相比，对