地下水中溶解性有机物的季节变化特征及成因-中国环境科学.PDFVIP

中国环境科学 2015,35(3) ：862~870 China Environmental Science 地下水中溶解性有机物的季节变化特征及成因 何小松 1,2,席北斗 1,2,张 鹏 3*,高如泰 1,2,李 丹 1,2,张 慧 1,2 (1.中国环境科学研究院,环境基准与风险评估 国家重点实验室,北京 100012 ；2. 中国环境科学研究院,地下水与环境系统创新基地,北京 100012 ；3.重庆市市政环 卫监测中心技术服务科,重庆 401121) 摘要：为阐明地下水中溶解性有机物(DOM)的分布特征与环境效应,联合三维荧光光谱 平行因子分析及主成分分析,研究了地下水中 DOM 的来源及随季节和空间变化特征,探究了地下水 DOM 组成对无机盐分布的影响.结果显示,地下水 DOM 主要来自微生物源,可鉴别出 4 种 荧光组分,4 种组分中,组分 1 和 3 为类蛋白组分,组分 2 和 4 属于类腐殖质组分.类蛋白组分来源差异较大,组成不稳定,其含量随季节变化明 显,春冬季含量低而夏秋季含量高;类腐殖质组分来源相似,组成稳定,随季节变化小.两类荧光组分,尤其是类蛋白组分,是地下水氨氮的主要 来源,可以影响地下水 pH 值.结果表明,三维荧光光谱结合平行因子和主成分分析,可以解析地下水中有机物的组成特征和季节变化规律. 关键词：三维荧光光谱；平行因子分析；地下水；溶解性有机物 中图分类号：X523 文献标识码：A 文章编号：1000-6923(2015)03-0862-09 The seasonal distribution characteristics and its reasons of dissolved organic matter in groundwater. HE Xiao-song1,2, XI Bei-dou1,2, ZHANG Peng3*, GAO Ru-tai1,2, LI Dan1,2, ZHANG Hui1,2 (1.State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China ；2.Innovation Base of Ground Water and Environmental System Engineering, Chinese Research Academy of Environmental Sciences, Beijing 100012, China ；3.Technical Services Section, Chongqing Municipal and Environmental Sanitation Monitoring Department, Chongqing 401121, China). China Environmental Science, 2014,35(3) ：862~870 Abstract ：To illuminate the distribution characteristics and environmental influences of dissolved organic matter (DOM) in groundwater, the source, spatial and temporal distribution characteristics of DOM were studied by fluorescence excitation-emission matrix spectra (EEM) combined with parallel factor (PARAFAC) analysis, and the influence of DOM on the distribution of inorganic salts was investigated as well. The results showed that the groundwater DOM was mainly mi