泡沫驱用稳泡体系的研究.docVIP

泡沫驱用稳泡体系的研究 刘晓玲 李娜 张贵才 王静 丁保东 仉莉 冯岸洲 (中国石油大学（华东）石油工程学院,山东 青岛 266555) 摘要：泡沫驱用起泡体系必须同时具有好的起泡能力和稳泡性能。Waring Blender 法和 Ross Miles 法评价均表明，α-烯烃磺酸盐起泡性能优异，但稳泡能力需强化。为此，本文对 聚丙烯酰胺、疏水缔合聚丙烯酰胺、聚乙烯吡咯烷酮等4 种增粘型稳泡剂，烷基醇、烷醇 酰胺、甜菜碱、改性硅醇等12 种非增粘型稳泡剂进行了研究。结果发现，增粘剂的加入会 显著提高泡沫的稳定性，相同质量分数的聚合物，稳泡能力由弱到强的顺序为：聚丙烯酰 胺（HPAM）、疏水缔合聚合物、聚乙烯吡咯烷酮，其中质量分数为0.1%的聚丙烯酰胺可使 泡沫的析液半衰期提高2.7 倍。起泡体系中聚合物的质量分数越大，稳泡性能越好，但起 泡能力会削弱。在非增粘型稳泡剂中，甜菜碱的稳泡效果较好，可以使60℃ 衰期增加1.7 倍，而烷醇酰胺、十二醇在低浓度时仅能使泡沫的消泡半衰期提高不到1 倍。 此外，论文还用微观可视化装置对泡沫在不同粘度油中的稳定性进行了探索，发现泡沫在 稠油的稳定性比在柴油中的稳定性高近30 倍。上述研究对泡沫驱用起泡剂的研制和稠油油 藏泡沫驱的数值模拟具有指导意义。 关键词：泡沫驱；泡沫稳定性；聚合物；甜菜碱；微观 Research on Foam Stabilizing System for Foam Flooding Xiaoling Liu, Na Li, Guicai Zhang, Jing Wang, Baodong Ding, Li Zhang, Anzhou Feng （Petroleum Engineering College, China University of Petroleum, QingDao 266555, China） ABSTRACT: The foaming system for foam flooding must have better foaming ability and foam stability. The results based on Waring Blender method and Ross Mile method showed that, α-olefin sulfonate has excellent foaming ability, but poor foam stability which is needed to be improved. So lots of foam stabilizers were investigated, which include 4 polymers and 14 non-polymers such as alkyl alcohol, betaine, alkanolamide and et al. The results showed that viscosifying agents can apparently help stabilize the foam. Among the 4 polymers, the foaming stability of polyacrylamide is best, 0.1% (wt) of which can increase liquid dropout half-time by 2.7 times. High mass fraction of polymer can greatly raise the foam stability, however they decrease the foam volume. Betaine exhibits better stabilizing effect among non-viscosifying foam stabilizers and can put up debubble half time by 1.7 times at 60 ℃ dodecanol can increase only by less than 1 time. In addition, the foam stability is investigated through microcosmic visual apparatus when foam is exposed to different viscosity of crude oil in this paper. It is testified that the foam stability in heavy oil is 30 times higher than