沼气同时脱硫脱碳过程模拟.docxVIP

沼气同时脱硫脱碳过程模拟马士魁1 ，胡万鹏2( 1． 安徽省阜阳市环境保护监测站，安徽阜阳 236033; 2． 嘉兴学院化学工程研究所，浙江嘉兴 314001)摘要 ［目的］模拟沼气同时脱硫脱碳过程模型的建立。［方法］采用 Aspen 流程模拟软件建立了沼气同时脱硫脱碳的过程模型，以此为 基础考察了吸收剂流量、浓度、温度和塔器的操作压力、塔板数等 沼气同时脱硫脱碳过程模拟 马士魁1 ，胡万鹏2 ( 1． 安徽省阜阳市环境保护监测站，安徽阜阳 236033; 2． 嘉兴学院化学工程研究所，浙江嘉兴 314001) 摘要 ［目的］模拟沼气同时脱硫脱碳过程模型的建立。［方法］采用 Aspen 流程模拟软件建立了沼气同时脱硫脱碳的过程模型，以此为 基础考察了吸收剂流量、浓度、温度和塔器的操作压力、塔板数等因素对脱除效率的影响。［结果］吸收剂 MDEA 的体积流量和浓度对 沼气中 H2 S 和 CO2 的脱除率有直接的影响; 考虑到脱除成本，采用相对较低的 MDEA 浓度，最佳质量分数为 10% 左右; 温度升高，吸收 速率降低，低温更有利于吸收脱碳操作。增加吸收塔的操作压力能够提高 H2 S 和 CO2 的脱除率，对 H2 S 具有较高的选择性; 对于含硫量 偏高的沼气，增加操作压力，有助于提高处理效果。吸收塔板数对脱硫脱碳效果的影响不明显，一般采取 11 块板左右能够达到分离要 求。［结论］该模拟结果对工业规模的吸收塔的设计和运行具有参考意义。 关键词 沼气; 脱硫脱碳; 过程模拟 0517 － 6611( 2012) 25 － 12594 － 02 中图分类号 S 216． 4 文献标识码 A 文章编号 Simulation of Simultaneous Desulfurization and Decarbonization Process from Biogas MA Shi-kui et al ( Fuyang Municipal Environmental Protection and Monitoring Station，Fuyang，Anhui 236033) Abstract ［Objective］ To establish a simulation model of simultaneous desulfuriziation and decarbonization from biogas． ［Method］ Based on Aspen process simulation software，a simultaneous desulfurization and decarbonization model was established，based on which the impact of absorbent flow，concentration，temperature as well as the pressure and stage number of towers on the removal rate was studied． ［Result］ The absorbent volume and concentration of MDEA had direct effect on the removal of H2 S and CO2 in biogas． Considering the cost of absorption process，low concentration of MDEA solution was selected，about 10% ． The absorption rate decreased with the increasing temperature，low temperature was better for the absorption process． Increasing the operation pressure will raise the absorption rate of H2 S and CO2 ，and show high selectivity for H2 S． To deal with high content of sulfur biogas，the increasing of operation pressure help to improve the process effect． The number of stages showed insignificant impact on the absorption results，generally 11 plates were selected to meet