改性生物炭对水体中头孢噻肟的吸附机制-中国环境科学.pdf

中国环境科学 2018,38(7) ：2527~2534 China Environmental Science 改性生物炭对水体中头孢噻肟的吸附机制 吴鸿伟 1,2*,陈 萌 1,黄贤金 1,苏宗杰 1,孙泰龙 1,谭晓燕 1,冯启言 2,3** (1.枣庄学院化学化工与材料科学学院, 山东 枣 庄 277160 ；2. 中国矿业大学环境与测绘学院,江苏 徐州 221116 ；3. 中国矿业大学低碳能源研究院,江苏 徐州 221116) 摘要：采用液相浸渍方法制备 3 种改性生物炭,采用红外光谱、扫描电镜、比表面积测定仪和元素分析仪等手段表征生物炭表面结构形貌和组成.以头 孢噻肟为探针分子,考察改性生物炭对头孢噻肟的吸附性能及吸附影响因素,并探究其吸附机理.结果表明,30min 时碱改性生物炭(BC-NaOH)对头孢噻 肟的吸附率为 83%,符合伪二级动力学方程(R20.99),吸附率显著大于其他几种材料.热力学研究表明,BC-NaOH 吸附头孢噻肟是自发放热过程.基于反 应热力学及吸附率影响因素分析,得出 BC-NaOH 吸附头孢噻肟的机理是疏水亲和作用和静电引力. 关键词：改性生物炭；头孢噻肟；吸附；机理 中图分类号：X131.2 文献标识码：A 文章编号：1000-6923(2018)07-2527-08 1,2* 1 1 Preparation of modified biochar for adsorption of cefotaxime in solution. WU Hong-wei , CHEN Meng , HUANG Xian-jin , SU Zong-jie1 1 1 2,3** , SUN Tai-long , TAN Xiao-yan , FENG Qi-yan (1.Department of Chemistry, Zaozhuang University, Zaozhuang 277160, China ；2.School of Environmental Science and Spatial Informatics, China University of Mining and Technology, Xuzhou 221116, China ；3.Low Carbon Energy Institute, China University of Mining and Technology, Xuzhou 221116, China). China Environmental Science, 2018,38(7)：2527~2534 Abstract ：Three kinds of modified biochar were prepared by liquid impregnation and characterized by Fourier transform infrared spectroscope, scanning electron microscopy, N2 adsorption-desorption isotherm and elemental analyzer. Cefotaxime was selected for examining the adsorption efficiency and mechanisms of the adsorbent. The results showed that alkali modified biochar (BC-NaOH) exhibited more excellent adsorption than other biochar in 30min. The adsorption efficiency of cefotaxime by BC-NaOH was up to 83% and the data fitted the