丙烯酸羟乙酯对丙烯酸酯改性水性聚氨酯性能的影响.docxVIP

·研究论文·丙烯酸羟乙酯对丙烯酸酯改性水性聚氨酯性能的影响朱晓丽姜绪宝张志国孔祥正*(济南大学化学化工学院 济南 250022)摘要 ·研究论文· 丙烯酸羟乙酯对丙烯酸酯改性水性聚氨酯性能的影响 朱晓丽 姜绪宝 张志国 孔祥正* (济南大学化学化工学院 济南 250022) 摘要 以异佛尔酮二异氰酸酯、二羟甲基丙酸和聚丙醚二醇等为聚氨酯原料, 丙烯酸丁酯、甲基丙烯酸甲酯、三羟甲 基丙烷三丙烯酸酯为丙烯酸酯类单体, 丙烯酸羟乙酯(HEA)为聚氨酯和聚丙烯酸酯间的偶联剂合成了丙烯酸酯改性水 性聚氨酯(PU-AC)乳液. 首先建立并验证了一种测定 PU 接枝率, 即 PU 与丙烯酸酯发生接枝的部分占 PU 总数的百分 比的方法, 然后探讨了加入 HEA 后的反应温度和 HEA 用量对 PU 接枝率、PU-AC 乳胶粒径、胶膜吸水率和交联度等 性能的影响. 随着 HEA 与 PU 预聚体反应温度和 HEA 用量的提高, 体系中的最终残余 NCO 逐渐降低. 当 HEA 用量低 于其加入前体系中残余 NCO 量时, 增加其用量使 PU 接枝率和 PU-AC 乳胶粒径逐渐增加; 当 HEA 用量大于体系残余 的 NCO 量后继续增加其用量对 PU 接枝率和 PU-AC 乳胶粒径的影响不大. 胶膜吸水率随着 HEA 用量的增加而降低. 关键词 丙烯酸羟乙酯; 偶联剂; PU 接枝率; PU-AC 复合乳液 Effect of Hydroxyethyl Acrylate on the Properties of Polyurethane-Acrylics Hybrid Latexes Kong, Xiangzheng* Zhu, Xiaoli Jiang, Xubao Zhang, Zhiguo (College of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022) Abstract Polyurethane-acrylics (PU-AC) hybrid latexes were prepared using isophorone diisocyanate, di- methylol propanoic acid and polypropylene oxides of different molecular weights as main materials for PU component, and butyl acrylate, methyl methacrylate and a crosslinker, trihydroxymethyl propanetriacrylate (TMPTA) as main acrylic monomers. Hydroxyethyl acrylate (HEA) was used as the coupling agent between PU and AC. In a first step, a method for evaluation of PU grafting to AC polymers was proposed and veri- fied through designed experiments. The influences of reaction temperature of HEA and NCO in PU pre- polymer and of amount of added HEA on properties of the final latex and of the polymer, for instance, PU grafting, particle size and distribution in final PU-AC latex, polymer crosslinking and water adsorption of latex films, were explored. With increase in the reaction temperature between HEA and NCO, the final re- sidual NCO gradually decreased. With increase in HEA amount relative to NCO, expressed as HEA/NCO in mole, the particle size and PU amount grafted to AC polymers both increased when the HEA/NCO was be- low 1