应用新型功能纳米碳涂层磁性复合材料去除污染土壤中Pb和Cr的实验研究.pdfVIP

Contents Abstract VI Keywords: VII List of Figures XI List of Tables XIII Acronyms XIV Chapter 1 Introduction and literature review 1 1.1 Research background 1 1.1.1 Sources of Lead and Chromium in Soil 2 1.1.2 Risks of Lead and Chromium Contamination in Soil 8 1.2 Research status at home and abroad 9 1.2.1 PTMs contaminated soil remediation 9 1.2.2 Functionalized carbon nanostructured/coated composites for soil remediation 12 1.2.3 Synthesis of carbon nanostructured based composites 13 1.2.4 Separation of adsorbent from the soil 14 1.3 Challenges and engineering hurdles 16 1.4 Research contents 17 1.5 Research Technical route 18 Chapter 2 Research program and experimental design 20 2.1 Research program 20 2.2 Experimental design 20 2.3 Materials 21 2.4 Analytical techniques and instruments 21 2.5 Computational analysis 22 Chapter 3 Synthesis, characterization of functionalized-nanocarbon sphere magnetic composite and soil 24 3.1 Experimental 24 3.1.1 Synthesis of MCCSPG 24 3.1.1 Instrumental Analysis 24 3.2 Results and Discussion 24 3.2.1 Physicochemical characterization of MCCSPG 24 3.2.2 Characterization of soil 29 3.3 Summary 31 Chapter 4 Adsorption isotherms and kinetics of Pb(II) and Cr(VI) in soil using Functionalized carbon coated composite MCCSPG 33 VIII 4.1 Experimental 34 4.1.1 Adsorption isotherm 34 4.1.2 Adsorption kinetics 34 4.1.3 Acid digestion 34 4.1.4 Instrumental Analysis 34 4.2 Results and discussion 35 4.2.1 Adsorption at different initial concentrations 35 4.2.2 Adsorption isotherms 35 4.2.3 Adsorption at different time interval 38 4.2.4 Adsorption kinetics 38 4.3 Summary 41 Chapter 5 Optimization of Pb(II) and Cr(VI) adsorption onto MCCSPG using Box- Behnken De