化学原理课件-英文课件-4+Quantun+.pptVIP

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化学原理课件-英文课件-4+Quantun+.ppt

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20XX年复习资料;Quantum Theory and the Electronic Structure of Atoms;7.1 Light and Classic Quantum Theory ;Wavelength (l);Electromagnetic radiation is the emission and transmission of energy in the form of electromagnetic waves.;2021/3/18;Planck’s Quantum Hypothesis (1901): ;The Particle Nature of Light: ;h v = p c;7.2 Dual Nature of Electron ;e- can only have specific (quantized) energy values light is emitted as e- moves from one energy level to a lower energy level;Ephoton = 2.18 x 10-18 J x (1/25 - 1/9);De Broglie (1924) reasoned that e- is both particle and wave.; 7. 3 Quantum Mechanical Description of Electrons in Atoms Schr?dinger Wave Equation;1. Application of Schr?dinger to Hydrogen Atom ;General solution for Hydrogen Atom; r distance from the nucleus;ml = -1;n: Principal quantum number;Energy of orbitals in a single electron atom;2. Application of Schr?dinger to Many-electron atoms;Energy of orbitals in a multi-electron atom;Order of orbitals (filling) in multi-electron atom;3. The Building-Up Principle of electrons in the orbitals:;What is the electron configuration of Mg?;Fe 26 electrons;Outermost subshell being filled with electrons;Ionization energy is the minimum energy (kJ/mol) required to remove an electron from a gaseous atom in its ground state.;;Electron Configurations of Cations and Anions;Electron Configurations of Cations of Transition Metals;+1;Atomic radius: one-half the distance between the two nuclei in two adjacent metal atoms.;Cation is always smaller than atom from which it is formed. Anion is always larger than atom from which it is formed.;2021/3/18;Exercises for Chapters 7 and 8: 7.16 7.79 7.80 7.104 7.106 7.114 8.114 ;相信梦想是价值的源泉，相信眼光决定未来的一切，相信成功的信念比成功本身更重要，相信人生有挫折没有失败，相信生命的质量来自决不妥协的信念。