铂系异丁烷脱氢催化剂研究.docxVIP

钳系异丁烷脱氢催化剂研究 Research of Pt catalyst for isobutane dehydrogenation 摘要 论文详细研究了钠系异丁烷脱氢催化剂的配方，从齐组分含量及载体等方面对 催化剂进行了筛选，以过渡金属和贵金属作为多组分催化剂的第三助剂，考察了助 剂类型及含量对催化剂性能的影响；最终以FPS?12催化剂为最优催化剂，并对不同 工艺条件下催化剂的脱氢性能进行了考察。得出了一?系列极有价值的实验结果和结 论，对此后异丁烷脱氢催化剂的研究有极大的参考价值。 研究包括以下几个方而： 1、 从催化剂屮齐组分含量，载体及氨水浸泡浓度等几方面对催化剂的配方 进行筛选，最终确定在Pt:Sn为1:1.5, Pt含量为0.4%, K含量为1%,载体可 为大孔氧化铝或中孔氧化铝，氨水浸泡浓度为11%时可以得到催化效果较好的催 化剂。该催化剂下，异丁烷转化率为30%左右，异丁烯选择性为80%以上。 2、 添加过渡金属Fe, Co, Ni, Zn, Ci?和贵金厲Pd, Ru, Au, Re作为催 化剂的第三助剂，考察不同助剂对催化剂的影响。在添加的五种过渡金屈助剂屮, 2%Cu助剂的加入使异丁烷转化率提高到35%左右，异丁烯选择性在80%以上。 在添加的四种贵金属助剂中，l%Au助剂的添加使异丁烷的转化率提高到40%以 上，异丁烯的选择性在80%以上，且持续时间在20小时以上。将该催化剂命名 为 FPS-12o 3、考察FPS-12催化剂下，工艺条件对脱氢性能的影响。确定最佳工艺条件 为：温度为600°C,进料空速为773/h,原料气与氢气流量比值为1:3左右。异丁 烷转化率在40%以上，异丁烯选择性在85%左右，该催化剂稳定性良好。 关键词:异丁烷；脱氢；钳系催化剂；助剂；工艺条件 Abstract This thesis explored the formula of platinum catalyst dehydrogenation in detail. To get the optimized catalyst .optimizated the catalyst from each component content and carrier selectionwere investigated; The transition metals and precious metals wereadded as a third additive multicomponent catalysts. The effect of additive type and content on the catalyst was investigated; At last, FPS-12 was the optimal catalyst. The influence of different process conditions on the catalyst performance were investigated.A series of valuable results and conclusions were obtained, which has enormous reference value for the study of isobutane dehydrogenation catalyst? This thesis containedseveral sections: The first part was focused on these aspect to optimize the recipe of catalysts such as content of components, carriers and the immersing concentration of ammonium hydroxide. Among these tests, we finally determined the optimal casre,as followed, the ratio of Pt to Sn was 1:1.5, the content of Pt was 0.4%, the content of K was l%.The carrier was macroporous AI2O3 or middle AbOs.The optimal expeimental results indicated that isobutane conversion rate was about 30% and the isobutene selectivitywashigher than 80%. The second part,