海德堡水泥中心培训教材—熟料矿物学和烧制技术.pptVIP

5thPresentation

第五讲

ClinkerMineralogy

and

BurningTechnology

熟料矿物学和烧制技术Contents

内容ClinkerPhases–GeneralOverview熟料相-概述FromRawMealtoClinker从生料到熟料DeterminationofClinkerPhases熟料相的测定MainClinkerPhasesandSecondaryComponents主要熟料相和次要成分Alite硅酸三钙石Belite斜硅钙石Aluminate铝酸盐Ferrite铁酸盐FreeLimeandPericlase游离石灰和方镁石AlkaliSulfates碱性硫酸盐ParametersInfluencingClinkerQuality影响熟料质量的要素ClinkerGrindability熟料的易磨性Conclusion结论ClinkerPhases–GeneralOverview

熟料相-概述Fromrawmealtoclinkerbyphasereaction

生料通过相反应变为熟料Reactionprocessesinarotarykilnwithpre-heater

装有预热器的回转窑中的反应过程Clinkercompositioninpercentages

熟料组成的百分比Quantitativedeterminationofmineralphasesinclinker

熟料中的矿物相的含量测定Boguemethod伯格法

Calculationofthephasecontentfromchemicalcomposition.由化学组成计算相含量。Opticalmicroscopy光学显微镜法

Countingofthephasesonpolishedandetchedmicrosections(referencemethod).在磨光并蚀刻过的显微切片上计算相（参考方法）。X-raydiffraction(XRD)X光衍射

DeterminationbyusingRietveldrefinement(mathematicalmodeling).使用里特维尔德精炼法测量（数学模型）。Calculationofthepotentiallyexistingphases(Bogue)

潜在现存相的计算(伯格法)Samplepreparationformicroscopy

显微镜法的样本准备Crushedclinkerisembeddedtogetherwitharesininamold将捣碎的熟料与树脂混合装入模具Cuttingofacrosssection切割一块横切片Polishingofthesurface磨光其表面Etchingwithliquidorvapor(acidlikeHNO3orHF).Thecolorsappear.用液体或蒸汽（HNO3或HF之类的酸）蚀刻。颜色显现出来。Magnificationfrom150to200times放大150至200倍Applicationofthemicroscopytoclinker

熟料生产中显微镜法的应用Rawmealburnability(homogeneity,coarseparticles,fineparticles)生料的可燃性（均匀性，粗糙的颗粒，精细的颗粒）Clinkerreactionsinthesinteringzone烧结区的熟料反应Residencetimeoftheclinkerinthesinteringzone熟料在烧结区的停留时间Clinkercoolingprocess熟料冷却过程Clinkerphases:Alite,C3S

熟料相：硅酸三钙石，C3SAliteisthenamefortechnicallyproducedC3Swithforeignionswhichareincorportedinthecrystallattice.硅酸三钙石是工艺上与杂质离子一同生产出的C3S的名称，这些杂质离子混合在晶格中。Inc