高等化工热力学课件Statistical_Mechanical_Ensemble (1).pdfVIP

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高等化工热力学课件Statistical_Mechanical_Ensemble (1).pdf

StatisticalMechanical

Ensembles

DiannanLu

DepartmentofChemicalEngineering

MicroscopicAndMacroscopicVariables

CentralquestioninStatisticalMechanics:

Ifparticles(atoms,Molecules,electrons,nuclei,orevenlivingcells)obeycertainmicroscopic

lawswithspecifiedinterparticleinteractions,whataretheobservablepropertiesofa

macroscopicsystemcontainingalargenumberofsuchparticles?

Examplesofmicroscopicandmacroscopicvariables:

Micr

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