筛选用于表面分子印迹材料的多孔碳微球.docVIP

  筛选用于表面分子印迹材料的多孔碳微球# 赵慧君1,2，杨永珍2,3，刘旭光1,2，许并社2,3** （1. 太原理工大学化学化工学院，太原 030024； 5 10 15 20 25 30 35 40 2. 新材料界面科学与工程教育部重点实验室(太原理工大学)，太原 030024； 3. 太原理工大学新材料工程技术中心，太原 030024） 摘要：以葡萄糖晶体为原料，采用低温水热法和退火处理制得多孔碳微球。利用扫描电子显 微镜、红外光谱仪、X-射线衍射仪、热重分析仪和孔径分析仪进行表征。结果表明：通过调 节低温水热反应中反应物浓度、反应时间、反应温度等参数，在葡萄糖溶液浓度 0.3 mol/L、 温度 180、时间 14 h 时，得到粒径尺寸均一、表面光滑、形貌规整并且具有一定溶剂分散 性的碳微球；退火后碳微球的尺寸均匀介于 100~700 nm 之间，孔径集中分布在 1.169~1.763 nm 之间，比表面积为 502.6 m2/g，表面具有羟基、羰基、羧基等含氧官能团。此多孔碳微 球有望在表面分子印迹聚合物的制备过程中省去表面氧化的步骤，提高进一步接枝的反应活 性，解决在表面分子印迹过程中修饰过程复杂的问题。 关键词：材料物理与化学；水热；葡萄糖；多孔碳微球；分子印迹 中图分类号：TB 332 Screening porous carbon microspheres for surface molecularly imprinted materials ZHAO Huijun1,2, YANG Yongzhen2,3, LIU Xuguang1,2, XU Bingshe2,3 (1. College of Chemistry and Chemical Engineering, Taiyuan University of Technology, TaiYuan 030024; 2. China Key Laboratory of Interface Science and Engineering in Advanced Materials (Taiyuan University of Technology), Ministry of Education, TaiYuan 030024; 3. Research Center on Advanced Materials Science and Technology, Taiyuan University of Technology, TaiYuan 030024) Abstract: The porous carbon microspheres (CMSs) were obtained after the annealing of CMSs, which were prepared by hydrothermal method at low temperature using the glucose crystal as raw materials in the reaction vessel. The samples were characterized by electron microscopy, infrared spectroscopy, X-ray diffraction, thermogravimetry and pore size analysis. The results shows that CMSs, with uniform size, surface smooth, a regular morphology and solvent dispersion, were prepared at optimum conditions of 0.3 mol/L glucose concentration, 14 h and 180℃ by adjusting the concentration of reactants, reaction time, and temperature in hydrothermal reaction; the annealed CMSs with a specific surface area of 502.6 m2·g-1 and ranging from 100~700 nm, had the pore sizes of 1.169~1.763 nm and several oxygen-containing functional groups including hydroxyl, carbonyl and carboxyl groups on their surfaces. As-obtained por