熔体状态与冷速对Pb-Sb90合金初生相生长形貌的综合作用.docVIP

  熔体状态与冷速对 Pb-Sb90 合金初生相生长 形貌的综合作用# 丰大顺，张文进，张先锋，高文龙，祖方遒** 5 10 15 20 25 30 （合肥工业大学，材料科学与工程学院，金属液固加工研究所, 合肥 230009） 摘要：本文首先探索了 Pb-90wt%Sb 合金熔体升、降温过程电阻率-温度行为，其结果提示 升温过程在 861-1100区间发生不可逆熔体结构转变。进而探讨了不同凝固条件下熔体状 态与冷速对其初生相（Sb 固溶体）结晶形貌的综合作用。结果表明：凝固过程冷速较低 时，转变前、后两种不同状态熔体凝固后初生相形貌均为小平面生长特征的棱角分明的多 面体。随着冷却速度的提高，初生相的棱角被钝化，且树枝晶比例逐渐增多；另一方面， 结构转变后的熔体状态增强了初生相形貌发生改变的这一效果。当冷速增至一定程度，转 变后结构状态的熔体凝固初生相形貌完全转化为非小平面生长特征，棱角分明的多面体已 不复存在。 关键词：材料加工工程；熔体状态；冷却速度；晶体形貌 中图分类号：TG146.1+4 Combined effects of melt status and cooling rate on crystal morphology of primary phase of Pb- Sb90 alloy FENG Dashun, ZHANG Wenjing, ZHANG Xianfeng, GAO Wenlong, ZU Fangqiu (Liquid/Solid Metal Processing Institute, School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, China) Abstract: This paper explores the resistivity-temperature behavior of Pb-90wt%Sb during heating and cooling processes firstly, the result shows that an irreversible melt structure transition occurs at 861-1100℃. The combined effects of melt status and cooling rate on crystal morphology of primary phase (solidus solution of Sb) with different solidification conditions are investigated. The result indicates that: the morphology of primary phase is angular polyhedron with faceted feature at lower cooling rate. With higher cooling rate, the angles of primary phase are passivatied, and the proportion of dendrite increase; On the other hand, melt status after structure transition strengthens this effect of morphology changes on primary phase. When the cooling rate increased to a certain extent, the morphology of primary phase of solidification structure which the melt underwent irreversible structure transition completely changes to non-faceted grow feature, and the angular polyhedron no longer exists. Key words: Materials Processing Engineering;melt status; cooling rate; crystal morphology 35 0 引言 晶体的形态不仅取决于晶体的结构（内因），还与其生长条件和生长过程（外因）有着 密切的联系[1]。特别是熔融熵介于 2-3R(R 为普适气体常数)之间的半金属，其生长方式介于 小平面与非小平面之间[2]。其晶体形貌受动力学因素影响很