V2O5含量对V2O5_WO3-TiO2体系NH3-SCR催化剂水热稳定性影响.docVIP

  V2O5 含量对 V2O5/WO3-TiO2 体系 NH3-SCR 催化剂水热稳定性影响# 史安举1，王欣全1，王军1，沈美庆1,2** 5 10 15 20 25 30 35 40 （1. 天津大学化工学院绿色合成与转化教育部重点实验室，天津 300072； 2. 天津大学内燃机燃烧学国家重点实验室，天津 300072） 摘要：V2O5/WO3-TiO2 催化剂的水热稳定性是制约其在柴油车尾气氮氧化物催化脱除中应用的 重要原因。采用湿法浸渍法制备不同 V2O5 含量（1wt%-6wt%）的 V-W-Ti 催化剂，系统研究了 钒含量对催化剂的催化活性及水热稳定性的影响。评价结果表明，V2O5 含量的增加促进了新 鲜样品的低温 SCR 活性。而 V2O5 含量为 1wt%样品表现出最优的抗水热老化性能，经 750、 10wt%H2O、空气及 12h 老化后，其在 250-500℃范围内仍具有 80%以上的 NO 转化率。随着 V2O5 含量进一步增加，催化剂水热失活严重。通过 BET、XRD、SEM、Raman 研究结果表明， 活性组分 V2O5 含量的增加促使锐钛矿型 TiO2 载体烧结以及 TiO2 由锐钛矿型向金红石型转变， 造成催化剂比表面积严重损失以及表面 WOx 物种的团聚，致使高 V2O5 含量样品水热老化后活 性下降。 关键词：氮氧化物脱除；氨选择性催化还原；钒-钨-钛催化剂；水热稳定性；钒含量 中图分类号：X511 Effect of different V2O5 content on the hydrothermal stability of V2O5/WO3-TiO2 based NH3-SCR catalyst SHI Anju1, WANG Xinquan1, WANG Jun1, SHEN Meiqing1,2 (1. Key Laboratory for Green Chemical Technology of State Education Ministry, School of Chemical EngineeringTechnology, Tianjin University, TianJin 300072; 2. State Key Laboratory of Engines, Tianjin University, TianJin 300072) Abstract: Hydrothermal stability of V2O5/WO3-TiO2 based NH3-SCR catalyst is a key factor for the catalytic NOx removal from diesel engines. A series of V-W-Ti catalysts with different vanadia content were prepared by the impregnation method, and the NH3-SCR activity and hydrothermal stability of the catalysts were studies. Increasing vanadia content can improve the low temperature SCR activity of the fresh catalysts. While the 1wt%V2O5/WO3-TiO2 catalyst exhibits the best hydrothermal aging resistance among the aged catalysts, showing above 80% of NO conversion during 250 oC -500 oC even after hydrothermal treatment at 750 oC in 10wt%H2O/air for 12h. Further increase of vanadia content only results in severe deactivation of the catalysts. The catalysts were characterized by BET, XRD, SEM and Raman. The main results show that increasing vanadia content will promote TiO2 sintering and TiO2 phase transition from anatase to rutile, which results in the loss of surface area