碱处理对钛氧膜表面能的影响论文.doc

PAGE 毕 业 论 文（设计） 题 目： 碱处理对钛氧膜表面能的影响 摘 要 近年来，钛及其合金被广泛地应用在医学、电子及光学等领域。经大量研究发现，钛的许多优异的性能与其表面的一层氧化膜有关。本文采用微弧氧化的方法在纯钛表面制备钛氧膜样品，然后采用碱处理法对样品进行表面改性，通过对不同碱处理时间改性后的样品进行表面能研究，获得处理时间对样品表面能的影响。结果显示，与未经处理的钛氧膜样品相比较，碱处理后的样品的亲水性明显要要优于前者，而表面能要稍大于未经处理的样品，表面能中的色散分量所占比值有所下降。同时，通过比较不同碱处理时间下的钛氧膜样品的表面能，发现随着处理时间的增长，样品与测试液体的接触角的变化呈下降趋势；而表面能虽然随处理时间的增加有一定的增大，但是增幅不大，并且处理时间为120分钟样品的表面能甚至还有所减小；但是表面能的极性分量与色散分量之比却随时间的增加而增大。 关键词：钛氧膜；碱处理；微弧氧化；表面能 Abstract In recent years, titanium and its alloys are wildly used in medical, electric and optical fields. Many researches about titanium and its alloys have been developed. It is found that its many outstanding performances are related with one kind of oxide film on its surface. There are many kinds of methods to prepare Ti-O films. In this paper，the method of micro-arc oxidation was used to prepare Ti-O films on the pure titanium substrate. And then the alkali treatment method was used to modify the surface of Ti-O films. By studying the surface energy of samples prepared under different alkali-treated time, it will be concluded that how the surface energy is influenced by the alkali treatment process. The results showed that the hydrophilicity of the samples of alkali-treated is significantly better than that of untreated samples. In addition, the surface energy of the alkali-treated is slightly larger than that of untreated, while the ratio of the dispersion component in its surface energy declined. Meanwhile，comparing the surface energy of samples under different alkali treatment time, it is found that the contact angle between the samples and the test liquid shows a downward trend with the increase of alkali-treated time. On the other hand, though there is some increase in surface energy, the value is slight. Still the surface energy of the sample whose treatment time is 120 minutes decreased while the ratio of polar component to dispersion component of surface energy increased. keywords：Ti-O film；alkali treated；micro-arc oxidation；surface