表面活性单体AMCAB在水溶液中均聚合动力学的研究.pdfVIP

《化学通报》在线预览版 表面活性单体 AMC14AB 在水溶液中均聚合动力学的研究 刘慷慨 高保娇* （中北大学化学工程系， 太原 030051 ） 摘要 采用溴酸钾-溴化钾法研究了阳离子型表面活性单体（2 －丙烯酰胺基）乙基十四烷基二甲基溴化铵（AMC14AB ）在水 溶液中的均聚合动力学，分别考察了引发剂浓度与单体浓度对聚合速率的影响，确定了聚合速率方程，分析了均聚合机理， 考察了温度对均聚合反应的影响，测定了聚合表观活化能。研究结果表明，由于 AMC14AB 在水溶液中的胶束化行为，使其 具有较快的聚合速率，于 60℃下聚合，40min 内转化率即可达到 80% 以上；AMC14AB 聚合速率方程为Rp k[M ]0.92[I ]0.48 ， 说明链终止为双基终止方式，引发过程与单体无关；聚合表观活化能为 80.72kJ/mol。 关键词 （2 －丙烯酰胺基）乙基十四烷基二甲基溴化铵 表面活性单体 聚合动力学 活化能 Studies on the Kinetics of Novel Surface Monomer AMC14AB Polymerizaton in Aqueous Solution * Liu Kangkai Gao Baojiao (Department of Chemical Engineering, North University of China, Taiyuan 030051) Abstract The polymerization kinetics of （2-acrylamido ）ethyltetradecyldimethylammonium bromide (AMC AB) in aqueous solution has been studied with KBrO -KBr method.The effects of initiator concentrations, 14 3 monomer concentrations and temperature on kinetics of AMC14AB polymerization in aqueous solutions have been studied, the polymerization rate equation was determined, and the polymerization active energy was measured. At the same time the polymerization mechanism was shown. The research indicated that the polymerization rate equation for AMC14AB is Rp k [M ]0.92 [I ]0.48 which displays that the chain termination reaction is according to the bimolecular mode, and the intitate process is independent on monomer concentration, and the apparent polymerization active energy is 80.72 kJ/mol. The reaction mechanism