Vacuum relaxation and annealing-induced enhancement of mobility of regioregular poly(3-hexylthiophene) field-effect transistors.pdf

Vacuum relaxation and annealing-induced enhancement of mobility of regioregular poly(3-hexylthiophene) field-effect transistors.pdf

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Vol18 No 11,N ovember 2009 ChinesePhysicsB ④an2d00l9OPCPhiunb.lPishhyinsg.SLotcd. 1674—1o56/2009/18(11)/5078—06 V_acuuin relaxat·i■on and1anneal1l●ng—l●nQ1ucea1 1 J ,- 1 ● 1 ● J ,● ● 1 ennanceinent otni ot)lllgY otregloregular 一 、- , 、_, poly(3_hexylthiophene)field—e cttransistors木 TianXue一Ln(田雪雁),XuZheng(徐 征),Zhaosll_Ling(赵谡玲), ZhangFu—Jun(张福俊),XuXu—Rong(徐叙珞),YuanGuang—cai(袁广才) LiJing(李 婧),SunQin—Jun(孙钦军),andWangYing(T 贽) InstituteofOptoelectronicsTechnology,BeijingJiaotongUniversity,Beijing100044,China KeyLaboratoryofLuminescenceandOpticalInformationrBeijingJiaotongUniversity). MinistryofEducation,Beijing100044China (Received1February2009;revisedmanuscriptreceived11March2009) Inordertoenhancetheperformanceofregioregularpoly(3_hexylthi0phene)(RR—P3HT)field—effecttransistors (FETs),RR—P3HTFETsarepreparedbythespin—coatingmethodfollowedbyvacuumplacementandannealing.This paperreportsthatthecrystalstructure,themoleculeinterconnection,thesurfacemorphology,and thechargecarrier mobilityofRR—P3HT filmsareaffected by vacuum relaxation and annealing.Theresultsrevealthatthefield—e仃ect mobilityofRR-P3HT FETscanreach4.17×10-2m /fV .s1byvacuum relaxationatroom temperatureduetoan enhanced localself-organization.Furthermore,itreportsthatanappropriateannealingtemperaturecan facilitatethe crystalstructure,theorientationandtheinterc0nnectionofpolymermolecules.Theseresultsshow thatthefield—effect mobility ofdeviceannealed at150。C fori0minutesinvacuum atatmosphereand followedby placementofr20ho

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