应用化学专业英语lesson5coordinationchemistry.pptVIP

Octahedral complexes with 3 bidentate ligands Example K3[Cr(C2O4)3] complex (tris chelate) Optical Isomerism Lesson 5 Coordination Chemistry Introduction Coordination chemistry Nomenclature of coordination compounds Isomerism of coordination compounds Coordination chemistry Complex Central metal ion bonded via coordinate covalent bonds to one or more molecules or ions are called ligands. Complex ion = complex with net charge. Coordination number = number of covalent bonds formed between metal ion and the ligands or ligand. Coordination chemistry Coordination compound Neutral substance made up of complex ion and another ion of opposite charge. (b) Neutral complex. Ligand Lewis base – contains at one nonbonding pair of electrons. Types of complexes Cationic complexes The complex ion has a positive charge. Example: [Co(NH3)6]3+ Anionic complexes The complex carries a negative charge. Example: [Ag (CN)2]- Neutral complex The complex does not carry a charge. Example: [Ni(CO)4] Double salts and coordination compounds Those which lose their identity in solution is called double salts FeSO4(NH4)2SO4. 6H2O ? Fe2+ + 2NH4+ + 2SO42- + 6H2O Those which retain their identity in solution is called complexes K4[Fe(CN)6] ? 4K+ + [Fe(CN)6]4- Who is Father of Coordination chemistry? Werner’s theory - 1893 Werner’s Theory Werner explained the nature of bonding in complexes based on the two types of valency Primary valency The number of charge on the complex ion. Secondary valency The number of ligand atoms coordinated to the metal. This is now called the coordination number. Coordination chemistry complex formation reactions Mn+ + pLx- M(L)pn-x (L = anion) Mn+ + pL M(L)pn+ ( L = molecule) Where Mn+ = Leiws acid ( center of coordination) L and Lx- = Leiws bases ( ligands) Common Ligands Monodentate ligands Contains only one donar atom Examples: H2O, NH3, CN- , SCN- , X- ( halide i