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中国科技论文在线
Improved Electrochemical Performance of Carbon-Coated
LiFeBO3 Nanoparticles for Lithium-ion Batteries#
1,2 2 1 2**
5 LI Zhaoping , WANG Yiping , HU Querui , YANG Ying
(1. College of Materials Science and Technology, Nanjing University of Aeronautics and
Astronautics, Nanjing, 210016, China;
2. State Key Laboratory of Mechanics and Control of Mechanical Structures, Nanjing University
of Aeronautics and Astronautics, Nanjing 210016, China)
10 Abstract : Carbon-coated LiFeBO3 nanoparticles have been successfully prepared by
surfactant-assisted ball milling and a size selection process based on centrifugal separation.
Monodispersed LiFeBO3 nanoparticles with dimensions of 10-20nm are observed by transmission
electron microscope. The introduced surfactant acts as the dispersant as well as the carbon source for
LiFeBO3 nanoparticles. Greatly improved discharge capacities of 190.4 mAhg-1 at 0.1C and 106.6
15 mAhg-1 at 1C rate have been achieved in the LiFeBO3 nanoparticles when cycling the cells between
1.0V and 4.8V. Meanwhile, the as-prepared micro-size LiFeBO3 electrodes show lower discharge
capacities of 142 mAhg-1 and 93.3 mAhg-1 at 0.1C and 1C rates. The post-treated LiFeBO3
nanostructure has drastically enhanced the electrochemical performance due to the short diffusion
length and ameliorated ele
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