LiFePO4纳米颗粒制备.pdfVIP

中国科技论文在线 LiFePO4 纳米颗粒制备# 段东红，李海霞，卫国强，张忠林，刘世斌** （太原理工大学洁净化工研究所，太原 030024 ） 5 摘要 ：LiFePO4 作为很有潜力的锂离子二次电池的正极材料，具有许多优点：170 mAh/g 的 高理论比容量，3.4 V 的充放电平台，高的热力学和化学稳定性，以及其廉价无毒给经济和 环境带来了益处。本文采用Sol-Gel 法，利用低成本的三价铁盐作为铁源，以柠檬酸既作为 还原剂，又作为螯合剂采用Sol-Gel 法制备，制备出了颗粒较小的纳米LiFePO4 。通过对不 同煅烧温度及保温时间的考察，得出在95% Ar，5% H2 混合气氛下，700℃、15 h 煅烧后得 10 到的LiFePO4 形貌与晶体结构最佳。 关键词：磷酸铁锂；溶胶凝胶法；包覆 中图分类号：O646 Synthesis of nanostuctured LiFePO4 15 DUAN Donghong, LI Haixia, WEI Guoqiang, ZHANG Zhonglin, LIU Shibin (Chemical Engineering Department, Taiyuan University of Technology, Taiyuan 030024) Abstract: Lithium iron phosphate is an interesting active cathode material for using in lithium secondary batteries, because it has a high theoretical capacity of 170 mAh/g and a flat discharge voltageat of 3.4 V. It also has high chemical and thermal stability, and because of its low cost and less 20 toxic material, it offers economic and environmental advantages.The nanoparticle of LiFePO4 was synthesized by sol-gel method using the low cost Fe3+, as a source of iron, the citric acid both as a reducing agent and a chelating agent. Through the investigation of the calcining temperature and heat preservation time, it is concluded that at the 95% of argon and 5% hydrogen mixed atmosphere, the best condition to get LiFePO4 crystal is 700 ℃, 15 h. 25 Key words: lithium iron phosphate; sol-gel; carbon coated 0 引言 LiFePO4 以其环保、价格低廉、热力学稳定性以及较好的循环稳定性，被广泛应用于便 携式车载动力电源。然而，LiFePO