CNTs增韧PHBV TPU复合材料的研究.pdfVIP

中国科技论文在线 CNTs 增韧 PHBV/TPU 复合材料的研究# 王世超，龚雪，相恒学，周哲，彭程，单桂芳，朱美芳** （东华大学材料科学与工程学院，纤维材料改性国家重点实验室，上海 201620 ） 5 摘要：为提高PHBV 与TPU 两相之间的相互作用力，改善复合材料的力学性能及热稳定性， 本文采用熔融共混法制备了PHBV/TPU/CNTs 复合材料，通过SEM、XRD 、DSC 、TG 、万 能试验机等对其表面形貌、晶体结构、热学性能以及力学性能进行了表征。研究结果表明， 添加CNTs 后PHBV 与TPU 两相界面未产生分离，两相之间的作用力有所提高；CNTs 的 加入促进了PHBV 的结晶且使其由熔融双峰变为熔融单峰；此外，PHBV/TPU/CNTs 复合材 10 料的力学性能及热稳定性也有了显著提高。相比纯 PHBV ，复合材料的初始降解温度提高 15℃，P/30T/3CNTs 复合材料的断裂伸长率提高1800%左右。 关键词：高分子材料；聚（3-羟基丁酸酯-co-3-羟基戊酸酯）；热塑性聚氨酯；碳纳米管； 增韧改性 中图分类号：TQ320.1 15 Preparation and Characterization of CNTs Reinforced PHBV/TPU Composites WANG Shichao, GONG Xue, XIANG Hengxue, ZHOU Zhe, PENG Cheng, SHAN Guifang, ZHU Meifang 20 (State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,College of Materials Science and Engineering, Donghua University, ShangHai 201620) Abstract: PHBV/TPU/CNTs composites with good mechanical properties and thermal stability were prepared by melt processing method. Surface morphology, crystal structure, thermal properties and mechanical properties of the composites were studied by SEM, XRD, DSC, TG and 25 universal testing machine. Results showed that the addition of CNTs improved the compatibility between PHBV and TPU effectively. In addition, the crystallinity of PHBV was increased and the two melting peaks of PHBV turned into a single one at the same time by the appearance of CNTs. What ’s more, the mechanical properties and thermal stability of composites were improved significantly. Initial degradation temp