土壤中植物有效锰的形态分级.docVIP

文章编号:1008-181X（2000）04-0294-04 土壤中植物有效锰的形态分级 司友斌1，2，王慎强1，马友华2，章力干2 （1：中国科学院南京土壤研究所，江苏 南京210008；2：安徽农业大学，安徽 合肥 230036） 摘要：用4种方法测定土壤有效态锰含量，并加以比较和评价，从而确定出最优的土壤有效锰测定方法。研究结果表明，采用一种顺序浸提的方法能比较准确地反映土壤的供锰状况，锰组分及其相应浸提剂为：易溶态锰（0.05 mol/L Ca(NO3)2提取）、弱吸附态锰（pH 8.5, CaDTPA-B4O7 ）、碳酸盐束缚态锰（石灰性土壤，用1.6 mol/L HNO3快速浸提）或专性吸附态锰（非石灰性土壤，pH 4.4，0.05 mol/L Ca(NO3)2 + 0.05 mol/L Cu(NO3)2提取）和氧化锰（pH 2.0，0.1 mol/L NH2OH(HCl）。由盆栽试验辣椒吸收的锰与土壤锰相关分析结果显示，易溶态锰是植物最易吸收的锰，其回归方程为：Y = -14.409 + 21.658 X，r =0.9938**（p≤0.01），Y为辣椒叶片锰含量，X为土壤易溶态锰浓度。 关键词：土壤锰；有效性；形态分级 中图分类号：S153.6 文献标识码：A Fractionation of Soil Manganese Forms to Plant Availability SI You-bin1, 2, MA You-hua2, ZHANG Li-gan2 ( 1: Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, China; 2: Anhui Agriculture University, Hefei 230036, China ) Abstract: In order to get the best way to determine soil available Mn, four methods had been done and been compared with each other. The result of experiments indicated that a sequential-extraction procedure could quantitatively estimate those forms of Mn in soils of significance to plant Mn availability. The Mn fractions and their extractants were: readily soluble Mn — 0.05 mol/L Ca(NO3)2 ; weakly adsorbed Mn — pH 8.5, CaDTPA—B4O7 ; carbonate—bound Mn ( calcareous soils)—rapidly extraction with 1.6 mol/L HNO3; specifically adsorbed Mn ( noncalcareous soils) —0.05 mol/L Cu(NO3)2 in 0.05 mol/L Ca(NO3)2 , pH 4.4; and oxide Mn — pH 2.0, 0.1 mol/L NH2OH(HCl. It showed from the result of relationship analysis between Mn uptake by pepper in pot experiment and tested soil Mn forms that: readily soluble Mn was the most readily Mn uptake by plant. Multiple regression equation was given: Mn content in pepper leaves = -14.409 + 21.658 readily soluble Mn, r =0.9938** ( p≤0.01 ). Key words：soil manganese; plant availability; fractionation 土壤中锰供给情况的评价和有效态锰的测定问题一直是重要的研究课题。一般认为对植物有效态锰是水溶态、交换态和易还原态锰，三者的总和称为活性锰。也有人认为并不是全部易还原态锰都对植物有效，有效部分约占1/20，即：有效态锰=水溶态锰+交换态锰+1/20易还原态锰[1]。也有人提出用稀酸（例如H3PO4、HCl、H2SO4）浸