【化学工程与工艺专业】【毕业设计+开题报告+文献综述】有机硅乳液的合成及其在皮革上应用研究.docVIP

（20 届） 毕业设计 有机硅乳液的合成及其在皮革上应用研究 摘要:合适结构的聚醚硅油用以皮革可以明显改善皮革手感及提升产品的实际使用性能。然而目前聚醚改性硅油合成工艺的催化剂用量较大，产品稳定较差且实际应用性能不够理想。本主要考察反应温度、反应时间、助剂种类及用量对氯铂酸催化活性的影响，并探求其内在反应机制，拟实现催化剂活性最大化。实验结果表明：当氯铂酸催化剂的活化温度为90℃时，催化活性最高，其转化率为68.9%；常见胺类助剂对氯铂酸的活性都有抑制作用，但抑制程度与助剂用量间的对应关系不明显；此外对氯铂酸催化加氢的反应动力学进行了研究，研究发现其为2级反应，活化能为。最后对合成产物进行了结构表征和实际应用性能的考察。关键词: Abstract: The silicone polyether with suitbale structue for leather，It can significantly improve the feel of leather and the actual performance of the product. However，the synthetic technology of polyether modified silicone oil need larger amount of catalyst，the product stability is poor and the actual application performance is not ideal. Therefore, this experiment investigated the effects of the reaction temperature, reaction time, type and amount of additives on the catalytic activity of chloroplatinic acid and to explore its inherent response mechanism, intended to achieve maximum catalytic activity. The result showed that when the chloroplatinic acid catalyst activation temperature is 90 ℃, the catalytic activity is highest, the conversion rate is 68.9%; Common amine additives can inhibit the activity of chloroplatinic acid, but the corresponding relationship of the degree of additive inhibition between the amount of additives is not obvious; In addition, the chloroplatinic acid catalyzed hydrogenation reaction kinetics were studied, the study found that it is 2 reaction, the activation energy is 32.48kJ/mol. Finally, the synthesized product was characterized and the performance of the practical application was investigated. Keywords: organosilicon； Polyether modified silicone oil；Feeling agent；.leather 摘要 I Abstract II 1 绪论 1 1.1 引言 1 1.2 国内外研究进展 2 1.2.1 有机硅乳液的合成 2 1.2.2 有机硅乳液在皮革中的应用 4 1.3 小 结 5 2 实验部分 7 2.1 原料及试剂 7 2.2 实验装置 7 2.3 实验操作 8 2.4 实验结果表征 8 2.4.1 Si-H键的含量测定 8 2.4.2 红外光谱检测 8 2.4.3 改性硅油的乳化 8 2.4.4 皮革手感感官评价 8 2.4.5 乳液稳定性测定 9 3 结果与分析 10 3.1 产物原料红外分析 10 3.2 不同温度下的转化率 11 3.3 不同助剂下的转化率 12 3.4 不同助剂量下的转化率 12 3.5 不同温度下不同时段的转化率 13 3.5.1 硅油的浓度