【化学工程与工艺专业】【毕业设计+开题报告+文献综述】POSS改性环氧树脂制备与性能研究.docVIP

（20 届） 毕业设计 POSS改性环氧树脂制备与性能研究 摘要： POSS具有三维笼状立体结构的有机—无机纳米杂化材料，可以有效提高环氧树脂的使用温度、抗氧化性能等。本文采用氯甲基POSS(CM-POSS)对E-51树脂/甲基四氢苯酐(简记为E-51/MeTHPA/TEA)体系进行改性研究。化学流变学研究表明：E-51环氧树脂经CM-POSS改性后室温粘度显著增加，而CM-POSS的引入只对E-51/MeTHPA/TEA体系的初始粘度有影响，对低温反应初始阶段的粘度变化影响并不明显。在反应的初始阶段，粘度不高于1500mPa·s时，E-51/MeTHPA/TEA/CM-POSS体系的化学粘度变化符合双Arrhenius经验公式。 关键词：环氧树脂；POSS；有机-无机杂化纳米复合材料；流变性能。 Abstract： POSS is a organic-inorganic hybrid nanocomposites , can improve the thermal properties and oxidation resistance of epoxy systems. In this paper, the triglycidyl p-aminophenol epoxy resin (E-51) was first modified by chloromethyl oligomeric silsesquioxanes (CM-POSS) and then cured by a kinds of curing agents, 4-methyl-tetrahydrophthalic anhydride (MeTHPA) arespectively. The chemo-rheology investigation indicates that the viscosity of E-51 resin was greatly increased after modified with CM-POSS, and the present of CM-POSS in E-51/MeTHPA/TEA had little influence on the initial viscosity, but no evidence was found that it had influence on the viscosity at the initial reaction stage. A rheological model based on dual-Arrhenius equation was established and used to simulate chemo-rheological behavior of the E-51/MeTHPA/TEA/CM-POSS system. The viscosity estimated by the model was in good agreement with that of the experiment results at the initialization reaction stage. Key words： Epoxy Resin; POSS; Organic-inorganic Hybrid Nanocomposites; Rheological Properties . 目 录 摘要 I Abstract II 1 绪论 I 1.1 前言 I 1.2 环氧树脂改性进展 2 1.2.1 聚合物改性环氧树脂 2 1.2.2 无机纳米离子改性环氧树脂 2 1.2.3 聚硅氧烷共聚改性环氧树脂 2 1.3 POSS改性环氧树脂研究进展 3 1.3.1 POSS简介 3 1.3.2 POSS改性环氧树脂历史进展 4 1.3.3 POSS改性环氧树脂机理 5 1.3.4 POSS改性环氧树脂研究现状 5 1.3.5 POSS改性环氧树存在的问题 6 1.4 POSS纳米结构化合物及聚合物应用领域 7 1.5 本课题研究的意义和目标 7 2 实验部分 9 2.1 仪器、试剂 9 2.2 实验步骤 9 2.3.1 CM-POSS改性环氧树脂流变特性研究 9 2.3.2 CM-POSS的加入量对E-51/MeTHPA/TEA体系粘度影响 9 2.3.3 E-51/MeTHPA/CM-POSS/TEA体系化学流变学研究 10 3 结果与讨论 11 3.1 E-51环氧树脂固化剂用量的确定 11 3.1.1 固化剂理论用量的确定 11 3.1.2 实际固化剂用量的确定 11 3.2 促进剂用量的确定 11 3.3 CM-POSS的加入对E