响应面法优化厌氧上清液除磷的研究.pdfVIP

中国环境科学 2014,34(1) ：72~77 China Environmental Science 响应面法优化厌氧上清液除磷的研究 * 吕景花,袁林江 ,张婷婷 (西安建筑科技大学环境与市政工程学院,陕西 西安 710055) 摘要：在用铁盐对厌氧段富磷上清液进行化学磷沉淀以实现磷的回收和达标排放的 SBR 系统中,为了减少铁盐化学除磷残余物可能对生 物处理系统的影响,采用 Box-Benhnken 中心组合试验原理和响应面分析法,选择 Fe:P 、混凝搅拌强度、絮凝搅拌强度、搅拌时间等为自变 量,残余铁离子为响应值,研究自变量之间的交互作用, 以期优化化学除磷条件.通过 Design-Expert 8.0 软件得到 1 个二次响应曲面模型. 得 出最佳除磷条件: Fe:P 比为 1.40:1,搅拌强度为 275r/min,快速搅拌时间为 30s,絮凝搅拌强度为 60r/min,絮凝时间为 18min,沉淀时间为 20min. 在此条件下,化学混凝后残余铁离子浓度为 0.37mg/L,化学除磷率大于 97.66%. 关键词：化学磷沉淀；响应面分析法；变量分析 中图分类号：X703.1 文献标识码：A 文章编号：1000-6923(2014)01-0072-06 Application of response surface methodology (RSM) to optimize chemical phosphate precipitation from phosphorus enriched supernatants of a SBR at anaerobic stage. LÜ Jing-hua, YUAN Lin-jiang*, ZHANG Ting-ting (School of Environment and Municipal Engineering, Xian University of Architecture and Technology, Xian 710055, China). China Environmental Science, 2014,34(1)：72~77 Abstract ：Ferric salt was used as precipitator for phosphorus removal from supernatant of a SBR at anaerobic stage to recovery phosphorus source. To reduce adverse effect of chemical residue on the microorganism and reclaim phosphorus resources as much as possible, Box-Benhnken center combination experimental principle and response surface methodology were adopted, rations of dosage of ferric salt to that of phosphate, agitation speed, flocculation reaction time were chosen as independent variable and residual ferric ion concentration for response value to explore the interaction among those parameters in this study. With the aid of Design-Expert 8.0 software, a quadratic curved surface model was obtained. The result showed that the optimum conditions to be a dose of 1.40:1molar ratio of ferric ion to phosphate, stirring intensity for 275r/min with 3