悬浮型光催化纳滤膜反应器对染料中间体H酸溶液的降解.pdfVIP

中国环境科学 2014,34(3) ：658~663 China Environmental Science 悬浮型光催化纳滤膜反应器对染料中间体 H 酸溶液的降解 袁秋生 1,倪广乐 2,张爱勇 3* (1.徐州工业职业技术学院化学工程技术学院,江苏 徐州 221140 ；2.徐州市环境监 测中心站生物室,江苏 徐州 221000 ；3.合肥工业大学土木与水利工程学院,安徽 合肥 230009) 摘要：在多组分条件下通过采用悬浮型光催化纳滤膜反应器进行目标污染底 H 酸的光催化降解效率及反应动力学研究,控制干扰污染 物吐氏酸和变色酸浓度分别为 5,10,20,25,40mg/L,控制 H 酸浓度 100mg/L 恒定不变.实验结果表明,在单组分光催化纳滤膜反应器中,在 C /C ≥0.7 条件下,降解过程遵循 L-H 零级(0~12min)与 L-H 一级(12~20min)的混合动力学模型;在多组分光催化纳滤膜反应器中,随着干扰 t 0 物浓度的增加,在 C /C ≥0.7 条件下(约 0~20min 反应时间段)其降解过程均对应地遵循 L-H 一级反应动力学模型.通过实验进一步证实,H 酸 t 0 光催化降解动力学的改变主要由耦合光催化反应器内底物和光催化剂表面 H 酸的浓度差异性引起. 关键词：光催化；膜分离；耦合过程；多组分体系；去除效率；反应动力学 中图分类号：X703.3 文献标识码：A 文章编号：1000-6923(2014)03-0658-06 Degradation behaviors of H-acid solution in suspended photocatalytic nanofiltration membrane reactor. YUAN 1 2 3* Qiu-sheng , NI Guang-le , ZHANG Ai-yong (1.School of Chemical Engineering Technology, Xuzhou College of Industrial Technology, Xuzhou 221140, China ；2.Xuzhou Bureau of Environmental Supervision, Xuzhou 221000, China ； 3.School of Civil Engineering, Hefei University of Technology, Hefei 230009, China). China Environmental Science, 2014,34(3) ：658~663 Abstract ：The removal efficiencies and degradation kinetics of the target H-acid from multi-component aqueous solutions in suspended photocatalytic nanofiltration membrane reactor were performed, the concentrations of co-existing Tobias acid and Chromotropic acid were set to 5, 10, 20, 25and 40mg/L respectively, while the target H-acid was set to be 100mg/L. The experimental results indicated that, in the single-component reaction system, the photocatalytic degra