玻璃纤维负载纳米二氧化钛薄膜降解亚甲基蓝的研究.pdfVIP

C30 玻璃纤维负载纳米二氧化钛薄膜降解亚甲基蓝的研究 1,2 1 1，2 林中信 万隆 张世英 (1. 湖南大学 材料科学与工程学院，湖南 长沙 410082；2.长沙学院 生物工程与环境科学系， 湖南 长沙 410003 ) 摘要：采用溶胶-凝胶法在玻璃纤维（GF ）表面负载纳米二氧化钛薄膜，制备GF /TiO2 薄膜复合光催化剂。利用 XRD 、 SEM 及 EDS 等对其进行表征，研究热处理温度对二氧化钛的晶型及薄膜形貌的影响，并通过对亚甲基蓝的光催化降解试验， 分析溶胶粘度、负载量、热处理温度之间的关系及对 GF /TiO2 薄膜复合材料的光催化性能的影响。结果表明，当溶胶粘度 为 36.0mpa.s，热处理温度为 550℃时，负载量为 5%的GF /TiO2 薄膜复合材料光催化活性最好，60min 内对亚甲基的降解率 为 85%，并且该催化剂便于回收，在重复使用中也表现出很高的活性。 关键词：玻璃纤维；纳米二氧化钛；光催化；亚甲基蓝； Research on degradation of methylene blue over nano-titanium dioxide thin film supported on glass fiber Lin Zhongxin1,2，Wan Long 1，Zhang Shiying1,2 (1. College of Material Science and Engineering, Hunan University, Changsha, 410082 Hunan, China ；2. Department of Biological and Environmental Science, Changsha University, Changsha, 410003, Hunan, China) Abstract: Composite photocatalyst of TiO /Glass fiber(TiO /GF) were prepared via sol-gel method. The 2 2 morphology and structure of the sample was characterized by SEM, the chemical composite and the crystalline were analyzed through XRD and EDS. The relation between collosol viscosity, temperature of heat treatment and loading amount was also analyed. And the photocatalytic activity of the sample to methylene blue was studied. Results indicated that the optimum photocatalytic condition was as follows: the collosol viscosity is 36.0mpa.s, the temperture of heat treatment is 550 ℃, the loading amount is 5%, the time is 60 mins. The optimum decomposition of methylene blue was 85%. Meanwhile ,they can be easily recovered from the reaction solution and reused with a