机械合金化Mo-25%25Cr二元粉末非晶研究.pdfVIP

M14 机械合金化 Mo-25%Cr 二元粉末非晶研究 杨作鹏，席生岐*, 尚飞虎, 康铜 （西安交通大学金属材料强度国家重点实验室，西安 710049） 摘要：采用机械合金化方法，对 Mo75Cr25 二元合金系统进行机械合金化的研究，机械合金化过程在搅拌 式球磨机上进行，通入氩气保护，球磨时间分别为3，6，9，12，15，18和30h，球料比为30:1，球磨后 的粉末粒度通过激光粒度仪获得，用X射线衍射仪对球磨后的合金粉末的结构进行了分析，通过扫描电镜 对复合粉末的形貌进行了分析，并对二元合金系统进行了热力学计算。结果显示，球磨过程中，粉末粒子 不断的被磨平、冷焊、断裂、再冷焊，球磨初期，产生的新鲜表面使粒子冷焊在一起造成粒子尺寸的增大， 随着球磨的进行，两种元素的衍射峰都存在着不同程度的宽化，Cr元素的峰强不断减小和宽化，经过12h 的球磨最终消失，形成了非晶，Cr元素衍射峰的消失是由粉末细化和元素在Mo中的固溶的结果。 关键词：Mo-Cr；机械合金化；热力学；非晶 Amorphous Analysis of Mechanical Alloying Mo-25%Cr Binary Alloy Yang Zuopeng, Xi Shengqi*, Shang feihu, Kang Tong （State Key Laboratory for Mechanical Behavior of Materials , Xi′ an Jiaotong University, Xi′ an 710049, China) Abstract: Mechanical alloying of Mo75Cr25 had been performed in a high energy plant for a range of milling time, the milling was performed under an inert argon atmosphere with an attritor mill. Milling times of 3, 6, 9, 12, 15, 18 and 30 h were used, keeping a ball to powder ratio of 30-1, The crystallite size produced after milling was determined by laser particle size analyzer, the structure of alloy powders was characterized by X- ray diffraction, the alloyed powders obtained were characterized by scanning electron microscopy in order to determine the particles morphology, at last we calculated the ability of amorphous form for Mo75Cr25 system with miedema theory. As the results demonstrated, during high-energy milling the powder particles are repeatedly flattened, cold welded, fractured and rewelded. In the early stage of milling, the new surfaces created enable the particles to weld together and this leads to an increase in particle size, as the mil