硫酸介质中钛铁试剂电极过程的阻抗研究.pdfVIP

第十二届全国有机分子电化学与工业学术会议论文集 硫酸介质中钛铁试剂电极过程的阻抗研究 * 徐艳 文越华 程杰 曹高萍 杨裕生 （北京防化研究院，北京，1000191） 摘要：采用循环伏安、低速线性扫描和交流阻抗技术，以石墨为电极，研究了硫酸介质中钛 铁试剂电极过程的阻抗组成，结果表明，在0.25～0.5 mol·L-1 的钛铁试剂，2~3 mol·L-1 的硫 酸电解液条件下，电极极化较小。采用交流阻抗技术研究了催化电极——石墨毡的改性处理 对钛铁试剂电极过程的阻抗影响，结果表明，石墨毡电极的氧化处理可以增加电极的比表面 积和含氧官能团的数量，从而提高电极催化性能，降低阻抗。应用优化电解液、改性石墨毡， -2 10mA cm 的电流密度下，钛铁试剂的单电极电压降仅为58～60 mV 。 关键词：循环伏安 线性扫描 阻抗技术 钛铁试剂 电极过程 中图分类号： O 646 ；TM911 Impedance techniques research of the electrode process of Tiron in acid solution Xu Yan, WEN Yue-Hua *, Cheng Jie, Cao Gao-Ping, Yang Yu-Sheng Research Institute of Chemical Defense, Beijing , 100191 Abstract: The electrode process impedance of Tiron is studied on the graphite electrode by using cyclic voltammetry, linear polarization, and impedance techniques. The results shown that the increase of Tiron and H2SO4 concentration facilitate decrease in impedance. Therefore, the -1 -1 optimal H SO concentration is 2~3 mol·L containing 0.25~0.5 mol·L Tiron. The influence of 2 4 graphite felt treatment on the electrode process impedance of Tiron is studied by impedance techniques. The results show that the oxidation treatment is benefit to increase the specific area and the oxygen group of the graphite felt, therefore, to improve the catalyze character of the electrode. By using the optimized electrolyte and the treatment graphite felt, the potential drop can -2 be as low as 58～60 mV under the current density of 10mA cm . Key words: Cyclic Voltammetry Linear Polarization Impedance Techniques Electrode Process