绿色荧光配合物8-氨基喹啉硫氰酸镉的合成、晶体结构和荧光性质.pdfVIP

， 第 26卷第 1期 无 机 化 学 学 报 Vo1．26No．1 2010年 1月 CHINESEJOURNALOFINORGANICCHEMISTRY l7l—l75 研 充 绿色荧光配合物 8．氨基喹啉硫氰酸镉 的合成、晶体结构和荧光性质 徐 衡 黄 良芳 任小明 (安庆师范学院化学化工学院，功能配合物安徽省重点实验室，安庆 246003) 关键词 ：镉的配合物 ：晶体结构 ；荧光性质 中图分类号：O614．24+2 文献标识码 ：A 文章编号 ：1001—4861(2010)01—0171—05 A GreenLuminescentCadmium ComplexContaining8-AminoquinolineLigand： Synthesis，CrystalStructureandEmissionSpectra XU Heng HUANG Liang—Fang REN Xiao—Ming ∽nhuiKe)Laborator)of几notionalCoordinationCompounds，SchoolofChemistryand Chemic(dEngineering,AnqingNormalUniversity,Anqing,Anhui246003) Abstract：Acomplex，Cd(8一aminoq1)(SCN)2(1)(8-aminoql=8一aminoquinoline)，wassynthesizedandstructurally characterized．TheCd ionexhibitsdistortedoctabedralcoordinationgeometryandeachSCN—anionsbridgingthe neighboringCd(8．aminoq1)unitsforma2Dsheetcoordinationpolymer，andfurtherextendedintoa3Dsupramo— lecularstructure through仃一7rweak interactions．The complexemitsgreen luminescenceatroom temperature． CCDC：737144． Keywords：cadmium complex；crystalstructure；luminescence Crystalengineeringhasgrownintoasubjectthat temperature．chemistshavemadea lotofeffortsfor attracts intense attention because controlling the architectureofsupramolecular dimensionalnetworks molecularorganization in the solid state can lead to based on covalent interaction．hydrogen bond and materialswithnovelsturcturesandpromisingproper— intermolecularcooperativeinteractions／l~141．Thesynthe— ties ．Amongthese．highlyluminescentcoordination sisofpolynuclearoreven polymeric complexeswith compoundshaverecentlygetconsidera