普光气田高密度甲烷包裹类型与油气演化和H2S成因.pdfVIP

ScientificJournalofEarthScience Month2013，Volume ．Issue ，PE1-10 O H G ccurrenceandGenesisofMultipleTypesof ighDensityMethaneInclusionsinPuguang asField木 DehanLiulXianmingXiao1HHiTian1JinxingData Hgang Wang3ChunYang2AnpingHu2JingkuiM i2 。 ． ． , , , , 1．StateKeyLaboratoryofOrganicGeochemistry,GuangzhouInstituteofGeochemistry,ChineseAcademyofSciences，Guangzhou 510640，China 2．CNPCInstituteofPetroleumExploration，DevelopmentandResearch，Beijing83000，China 3．CNPCSichuanBranch，Chengdu610081，China Abstract Basedonmicro-Ramanspectroscopicanalysisofagreatquantityofinclusions，threetypesofhighdensiyt mehtaneinclusions wereidentifiedinthepetroleum reservoirofPuguanggasfield．TypeIinclusionsoccurincalcitemineralsofcarbonaterocksin gasreservoir,nadtheirRamanspectrashow 2910-2912cm peakscharacteristicofhighdensiyt methaneandappraentpekas characteristicofH2S aswellaspeakschraacteristicoftraceamountofCO2，butdonotshow peakscharacteristicofsolid pyrobitumen；Tpy eIIinclusionsoccurinearly-formedcalcitemineralsincarbonatereservoir,andtheirRamanspectranotonly show peakscharacteristicofhighdensitymethane，butalsoshow D andG peakschraacteristicofsolidpyrobiutmen，basically withnopeaksforH2S；TypeIIIinclusionsraehighdensitymethaneinclusionstrapped inquartzmineralsintheupperclastic reservoir,theirRamanspectramayormay notshow pekaschraacteristicofpyrobitumen，butbasicallyexhibiting no peaks characteristicofH2S．ItcanbeconcludedthatTypeIhighdensiyt methnaeinclusionsmaybyformedatthestageofhigh temperaturecrackingofoilreservoir，sinceinwellcementedreservoirs，notonlyagreatamountofmethanewouldbegenerated butalsoH2S—bearingfluidwouldbeformedasaresultofthemr alche