烷基磷酸酯钾盐性能研究.pdfVIP

烷基磷酸酯钾盐性能的研究 孙玉郑帼刘燕军 (天津工业大学高新技术实业公司天津300160) 摘要研究了影响烷基磷酸酯钾盐(PK)乳液粒径的因素，并且从宏观及微观两方面 讨论了PK对聚酯短纤维性能的影响。结果表明，乳液粒径随着pH值及中和温度的升高 而减小；烷基磷酸酯钾盐的单、双酯的比及环境的温湿度对纤维的抗静电性有较大的影 响；而PK乳液的粒径对其影响不大，但对纤维的摩擦特性有显著的作用，即随着PK乳液 粒径的减小，纤维的平滑性下降，集束性增加；当吸附量为0．1％时。PK乳液能较好地包 裹住纤维表面，当吸附量大于0．3％时，C18PK在纤维表面的堆积多于C，，PK。 关键词烷基磷酸酯钾盐；聚酯短纤维；粒径；乳液；抗静电性；摩擦特性 Researchon ofPotassiumSaltsof Properties Alkyl-—phosphate SUN地，ZHENGGuo，LIUYah—如再 (Hi—technicalCo．，Ti舳jinPolytechnicUniversity，Tianjin300160) Abstract：Thefactors the sizeof saltsof influencingparticle potassiumalkyl——phosphate PKon werestudied．In of fibreweredis— (PK)emulsion addition，The properties polyesterstaple cussedfromboth and inthis results thatthe macroscopicmicroscopicaspects paper．Thesuggested sizeofPKemulsiondecreasedwiththeincreasesofthe valueand particle pH neutralizingtemper- and had anti— ature．Themono／diesters considerableinfluenceOilthe ratio，temperaturehumidity static offibre．The sizeofPKhadlittleinfluenceontheantistatic but property particle property influencethefrictional of fibre．The decreasedand marked on propertypolyesterstaple lubricity increasedwithadecreasein sizeofPKemulsion．Thesurfaceof cohesion particle polyesterstaple fibrecouldbecoveredwell PKwhenthe amountwas resu]- by absorption 0．1％，whereas