黄河三角洲饮用水痕量溴酸盐的检测研究.pdfVIP

黄河三角洲饮用水痕量溴酸盐的检测研究 刘晓萍， 赖荣梅 ，张延军 （胜利油田供水公司水质检测中心 山东东营 257097） 摘要：溴酸盐是公共饮用水体系采用臭氧消毒过程中与其中的溴化物产生的一类无机消 毒副产物。黄河三角洲饮用水体系由于大量采用人工水库蓄水，饮用水中含有高浓度强弱离 子对痕量溴酸盐检测产生很大影响，本文就生活饮用水中离子色谱法检测痕量溴酸盐进行了 深入探讨，通过大体积进样和水样预处理措施，在检测精密度、最低检出限和加标回收方面 均达到相关要求。 关键词：溴酸盐、离子色谱仪、生活饮用水、臭氧、黄河三角洲 Study on the of detection trace Bromate in drinking water of the Yellow River Delta LIU Xiao-ping, LAI Rong-mei, ZHANG Yan-jun （Water Quality Testing Center of Water Supply Company, Shengli Petroleum Administration, Dongying 257097, Shandong province ） Abstract: Bromate is an inorganic disinfection byproducts which was produced by bromide in ozone disinfection process of public water systems. Yellow River Delta drinking water system use artificial reservoirs extensively in that the water contains strong and weak ions of high concentrations, which had a significant impact on the detection of trace bromate. This paper had a in-depth discussions on detection of trace bromate in drinking water used Ion Chromatography by large volume injection and water samples pretreatment measures. And it proved that the detection precision, minimum detection limits and recovery efficiency for standard doping all met the needs. Key words: Bromate; Ion Chromatograph; Drinking water; Ozone; Yellow River Delta . 1 前言 臭氧氧化作为一种可以全面改善饮用水水质的处理技术，在饮用水深度处理中的应用 - - 日益普遍。但研究表明，含溴离子(Br)水在臭氧氧化过程中会产生溴酸盐(Br0 )，溴酸盐 3 被认为是动物和人类潜在致癌物质 。当人长期饮用含0.000 5 mg／L溴酸盐的水时，其致 癌率为万分之一[1]。溴酸盐在高剂量时具有遗传毒性，《生活饮用水卫生标准》GB5749—2