中国化学会第九届全国有机化学学术会议（第二轮通知）.pdfVIP

798 高 等 学 校 化 学 学报 Vo1．36 [14] NsthH．，SchlegelA．，SuterM．， Organomet．Chem．，2001，621，231_241 [15] KoB．T．，ChaoY．C．，LinC．C．，Inorg．Chem．，2000，39，1463—1469 [16] BenjaminM．J．S．，GordonW．F．，Inorg．Chem．Act，2000，297，206—216 [17] AppiahW．O．，DeGreeffA．D．，RazidloG．L．，SpessardS．J．，PinkM．，YoungJ．V．G．，HofmeisterG．E．，Inorg．Chem．，2002， 41．3656— 3667 [18] ChenH．Y．，ZhangJ．B．，LinC．C．，ReibenspiesJ．H．，MillerS．A．，GreenChem．，2007，9，1038--1040 [19] SaveM．，SchappacherM．，SoumA．，Macromo1．Chem．Phys．，2002，203，889--899 Synthesis，Characterization ofM ethoxyl-bridgedAluminium-lithium HeterobimetallicComplexandCatalysisfortheRing-opening Polymerization ofs-Caprolactone WANG Lei ，YANG Li，GAO Chengyong (KeyLaboratoryofEco—Environment—RelatedPolymerMaterials，MinistryofEducationofChina， KeyLaboratoryofGansuPolymerMaterials，CollegeofChemsitryandChemicalEngineering， NorthwestNormalUniversity，Lanzhou730070，China) Abstract Themethoxyl—bridgedaluminium—lithiumheterobimetalliccomplex[(L)Al(2一OMe)Li(THF)3]2 (1)wassynthesizedandstructurallycharacterized．Reactionof2，6一bis(3，5一bis—t—butyl-2一hydroxybenzy1)-4一 t-butylphenol(H3-L)withn-BuLiandAI(CH3)3inamolarofratio1：1：1inTHFprovidesmethyl- aluminium—lithiumphenoxide[(L)A1(CH3)Li]．OxidationofthephenoxidebyO2inairgivestargetproduct 1inquantitativeyield．Catalysisbycomplex1forring—openingofs—caprolactone(-CL)wasstudied．Experi— mentalresultsindicatethatcomplex1couldcatalyzes—CLwithhighconversionandnarrowpolydispersityeven inanairatmosphere． Keywords Methoxyl；Heterobimetalliccomplex；Catalysis； -Caprolactone；Ring-openingpolymerization； Polycaprolactone (Ed．：W ，Z) 十SupposedbytheGansuProvincialNaturalScienceFoundationofChina(No．145RJZA188)，theYoungTeacherResearchFoundationof NoahwestNormalUnivers