基于超分子环糊精的共聚物合成和其包络吸附性能研究.pdfVIP

基于超分子环糊精的共聚物合成及其包络吸附性能研究* 孙朝阳，申明星，吕慧，王楠，曹贵平 （华东理工大学化学工程联合国家重点实验室，上海 200237 ） 摘要：分别合成了异氰酸酯-环糊精共聚物和苯乙烯- 甲基丙烯酸甲酯-环糊精共聚物，并对聚合物的包络吸 附性能进行了研究。利用SEM、FT-IR 、DSC 、TGA、XRD 和N2 吸附的方法对得到的聚合物的物理化学性 质进行了表征。在低浓度联苯胺中考察了温度和时间对吸附过程的影响，Freundlich 方程可很好地描述含环 糊精共聚物的吸附包络行为，并且计算得到了吸附过程中的∆HΘ，∆SΘ 和∆GΘ 的值分别为-18.5272kJ/mol ， -66.8854J/(mol·K)和-257.4530J/mol 。使用超临界二氧化碳对环糊精-苯乙烯- 甲基丙烯酸甲酯共聚物进行发泡 以改善聚合物的表观形貌。分别采用发泡前后的环糊精聚合物对芳香胺类化合物进行了吸附研究。在吸附 动力学研究中发现，吸附在60 分钟达到平衡，且吸附动力学过程能够用拟二级动力学来描述。由于芳胺分 子结构和极性的差异，环糊精聚合物对各个物质的吸附量大小为：对甲苯胺苯胺联苯胺邻甲苯胺。 Freundlich 方程和Langmuir 方程都能够较好的拟合吸附的热力学平衡过程。 关键词：β-环糊精；共聚物；芳香胺；包络吸附 中图分类号：TQ 316.6 文献标识码：A Introdction of β-Cyclodextrin into Copolymer Matrix and Its Inclusion Adsorption Properties Zhao-Yang Sun, Ming-Xing Shen, Hui Lv, Nan Wang, Gui-Ping Cao (State Key Lab of Chemical Engineering, East China University of Science and Technology, Shanghai 200237) Abstract ： Two kinds of β-cyclodextrin-hexamethylene diisocyanate copolymer and β-cyclodextrin-styrene-methyl methacrylate copolymer were synthesized, and their inclusion adsorption behavior was investigated. The physical and chemical properties of CD copolymer were characterized by SEM, FT-IR, DSC, TG, XRD and N2 adsorption. The equilibrium of the inclusion adsorption on β-cyclodextrin-hexamethylene diisocyanate copolymer could be described Θ Θ Θ by Freundlich equation and the thermodynamic constants ∆H , ∆S and ∆G were -18.5272kJ/mol, -66.8854J/(mol·K), and -257.4530J/mol, respectively. β-Cyclodextrin-styrene-methyl methacrylate copolymer was foamed by supercritical CO2 to improve its porosity. The quantities of aromatic amine compounds adsorbed on β-CD copolymer reached equilibrium within 60 mins. With the influence of molecular structure and hydrop