V-Ti-Cr系储氢合金吸氢动力学机制研究.pdfVIP

V-Ti-Cr 系储氢合金吸氢动力学机制研究 裴沛，宋西平，惠希东，陈国良 （北京科技大学新金属材料国家重点实验室） 摘要：通过试验测试及动力学方程计算研究了(TiCr) V （x=5,10,35）钒系固溶体合金吸氢动力学 1-x x 机制.结果显示,随着钒含量的增加,合金由Laves单相结构逐渐转变为Laves和V基固溶体两相结构, 最终转变为单相 V 基固溶体结构;相应地,其吸氢机制也由化学反应控制,逐渐转变为形核和长大机 制,最终转变为三维扩散机制.吸氢动力学机制不同,表现出其吸氢速率不同,化学反应控制的吸氢过 程速度快而三维扩散机制控制的吸氢过程速度减慢. 关键词:钒系固溶体;储氢合金;动力学 中图分类号： 文献标识码：A 文章编号 : Study of the kinetic mechanisms of hydrogen absorption in V-Ti-Cr alloys Pei Pei, Song Xiping, Hui Xidong, Chen Guoliang (State Key Lab for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China) Abstract : The kinetic mechanisms of (TiCr)1-xVx (x=5,10,35) alloys were investigated based on experimental tests and kinetic function calculations. The results show that with the increase of vanadium content the microstructure transforms from primary single Lavas phase to Lavas and V-based solid solution double phases, finally to the V-based solid solution single phase. Correspondingly the kinetic mechanisms of hydrogen absorption in these alloys are found to be controlled first by the, and then controlled by nucleation and growth mechanism, finally by a 3-dimensional diffusion mechanism. With the change of kinetic mechanisms, the kinetic reaction rate varies sharply, with the fast chemical reaction mechanism and slow 3-dimensional diffusion mechanism. Key words: V-based solid solution; hydrogen storage alloys; kinetics V-Ti-Cr 系储氢合金是近年来备受关注的 道,需进一步研究和探讨.本文利用试验测试以 一种储氢合金,具有储氢量大,容易活化,吸放氢 及动力学方程计算,对不同钒含量的 V-Ti-Cr 温度适中,抗粉化能力强等优点,但其吸放氢的 储氢合金的动力学机制进行了研究,取得了有益 动力学性能较差,吸放氢滞后现象严重,阻碍了 的结果. 其实际应用.最近的研究表明[1～3],当钒含量小于 1 试验过程及动力学计算方法 5%(mass%)时,其室温下吸放氢