电解废液净化技术定量研究与实践.pdfVIP

电解废液净化技术定量研究与实践 路 艳 （合肥铜冠国轩铜材有限公司，安徽合肥 230601 ） 摘要：本文以电解铜箔冲洗废液为研究对象，并以传统石灰混凝法处理电解废液为研究基础。列举了传统石灰混 凝法处理电解废液在生产过程出现的问题：固废泥渣产生量大；絮凝时斜板沉淀池内出现矾花絮团现象。本文通 过实验研究发现采用液碱作沉淀剂，PAM 作絮凝剂，处理电解铜箔废液效果较显著。投入生产使用，中试结果表 明采取定量化分析处理电解铜箔废液，固废泥渣量将减少约70%，PAM 絮凝剂使用量将减少约 60%，并能够连 续稳定达到电镀污染物排放标准。 关键词：电解废液；沉淀剂；絮凝剂 Research and Practice of Quantitative Techniques for Purifying Waste Electrolyte LU Yan （Hefei copper crown and copper. Co., Ltd., Hefei, 230601, China ） Abstract: This paper study the electrolytic copper foil flush waste. Base on study of treating heay metal ions wastewater by lime-flocculation has been carried on. Cited a problem with traditional lime coagulation process electrolytic waste in the production process appears. For example: large amount of solid waste generated sludge. When flocculation appear inclined plate sedimentation tanks alum tidbits group phenomenon. In this paper, experimental studies have found the use of caustic soda as a precipitating agent, PAM as a flocculation, electrolytic copper foil waste treatment effect is more significant. Put into production use, the results showed that taking quantitative analysis of electrolytic copper foil waste treatment, solid waste sludge volume will be reduced by approximately 70%, PAM flocculation consumption will be reduced by approximately 60%, and be able to achieve stable continuous plating emission standards. Keywords : waste electrolyte, precipitant, flocculation 随着工业生产的发展，含有电解废液废水不断增加，并迅速的破坏着环境，严重危害人体健康[1] 。目 前处理此类废水主要采用石灰混凝法处理[2] 。在采用上述方法中，为了确保达标排放，往往只是定性判断 石灰及絮凝剂的加药量。一般 pH 值控制在 11~12 之间，定性判断絮凝剂的加药量为形成大而密实的矾花。 但采